Synthesis of methyl 4-(9H-carbazole-9-carbanothioylthio) benzoate: electropolymerization and impedimetric study

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dc.authorid0000-0002-1806-0330
dc.authorscopusid9735216100
dc.authorscopusid56503880700
dc.authorscopusid54792801600
dc.authorscopusid54941444900
dc.authorwosiduludag, Nesimi/AAB-1353-2020
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorUludağ, Nesimi
dc.contributor.authorArican, Fatih
dc.contributor.authorKarazehir, Tolga
dc.date.accessioned2022-05-11T14:30:53Z
dc.date.available2022-05-11T14:30:53Z
dc.date.issued2015
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractMethyl 4((9H-(carbazole-97carbanothioylthio) benzoate (MCzCTB) was chemically synthesized and characterized by FTIR, H-1 NMR, and C-13 NMR. A novel synthesized monomer was electropolymerized on a glassy carbon electrode (GCE) in various initial molar concentrations of [MCzCTB](0) = 1, 3, 5, and 10 mM in 0.1 M NaClO4/CH3CN and 1 M H2SO4 center dot P(MCzCTB)/GCE was characterized by cyclic voltammetry, Fourier transform infrared-attenuated transmittance reflectance, scanning electron microscopy-energy dispersive X-ray, and electrochemical impedance spectroscopy. The capacitive behavior of the modified electrode was obtained by Nyquist, Bode-magnitude, and Bode-phase plots. The highest capacitance at low frequency was obtained as similar to 53.1 mF cm(-2) from Nyquist plot and 19.454 Fg(-1) at a scan rate of 10 mV s(-1) for [MCzCTB](0) = 1.0 mM. CS2 and OCH3 groups are electron-withdrawing and electron-donating groups in the monomer structure. These groups affect the polymerization and capacitive behavior of the polymer. The polymer may be used for supercapacitor and biosensor applications in the future.
dc.description.sponsorshipScientific and Technological Council of Turkey (TUBITAK) ProjectTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-110T791]
dc.description.sponsorshipThis work supported by the Scientific and Technological Council of Turkey (TUBITAK): TBAG-110T791 Project.
dc.identifier.doi10.3906/kim-1401-59
dc.identifier.endpage205
dc.identifier.issn1300-0527
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84922213172
dc.identifier.scopusqualityQ3
dc.identifier.startpage194
dc.identifier.urihttps://doi.org/10.3906/kim-1401-59
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7212
dc.identifier.volume39
dc.identifier.wosWOS:000349741100018
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorUludağ, Nesimi
dc.institutionauthorArıcan, Fatih
dc.institutionauthorKarazehir, Tolga
dc.language.isoen
dc.publisherScientific Technical Research Council Turkey-Tubitak
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectMethyl 4-((9H-(carbazole-9-carbanothioylthio) benzoate
dc.subjectelectrochemical impedance spectroscopy
dc.subjectcapacitor
dc.subjectelectropolymerization
dc.subjectsynthesis
dc.subjectSEM images
dc.subjectElectrochemical Impedance Spectroscopy
dc.subjectCarbon-Fiber Microelectrodes
dc.subjectElectrode Materials
dc.subjectCopolymer Formation
dc.subjectThin-Films
dc.subjectPolypyrrole
dc.subjectCarbazole
dc.subjectPolymers
dc.subjectPolyaniline
dc.subjectDerivatives
dc.titleSynthesis of methyl 4-(9H-carbazole-9-carbanothioylthio) benzoate: electropolymerization and impedimetric study
dc.typeArticle

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