Synthesis, photophysical and antioxidant properties of pyrrolo[3,2-c]carbazole and dipyrrolo[3,2-c:2,3-g]carbazole compounds

Basit Öğe Kaydı
dc.authorid0000-0002-7347-2223
dc.authorid0000-0002-3579-8062
dc.authorid0000-0001-9386-4892
dc.authorid0000-0003-4163-9962
dc.authorscopusid26029066300
dc.authorscopusid34168278000
dc.authorscopusid35866927300
dc.authorscopusid57204631537
dc.authorscopusid55326408200
dc.authorscopusid55308985300
dc.authorwosidk, h/ABA-1339-2020
dc.authorwosidŞenkuytu, Elif/ABI-5315-2020
dc.authorwosidSengul, Ibrahim Fazil/AAG-4368-2019
dc.contributor.authorBingül, Murat
dc.contributor.authorŞenkuytu, Elif
dc.contributor.authorBoga, Mehmet
dc.contributor.authorUslu, Tugce Nur
dc.contributor.authorKandemir, Hakan
dc.contributor.authorŞengül, İbrahim Fazıl
dc.date.accessioned2022-05-11T14:31:03Z
dc.date.available2022-05-11T14:31:03Z
dc.date.issued2019
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractThe synthesis of (6-ethyl-1,6-dihydropyrrolo[3,2-c]carbazol-2-yl)methanol 5 and (6-ethyl-6,11-dihydro-1H-dipyrrolo[3,2-c:2,3-g]carbazole-2,10-diyl)dimethanol 6 were achieved via the reduction of methyl pyrrolo carbazole carboxylate 3 and methyl dipyrrolo carbazole carboxylate 4, respectively. The structures of hydroxymethyl-pyrrolocarbazoles 5 and 6 were supported by FT-IR, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, H-1 and C-13 NMR spectroscopy. The photophysical properties of the targeted compounds 3-6 were investigated by employing absorption and fluorescence spectroscopy in different common organic solvents. Also, the fluorescence lifetime ((F)) of the compounds was measured utilizing a time-correlated single-photon counting technique in tetrahydrofuran. Antioxidant activities of compounds 3-6 were determined by employing three different assays, namely DPPH radical scavenging, ABTS cation radical decolarization and cupric reducing antioxidant capacity. The results revealed that the ABTS cationic scavenging activity assay was found to be the most sensitive method for the determination of inhibition values.
dc.description.sponsorshipResearch Fund of the Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [113Z159]
dc.description.sponsorshipWe thank the Research Fund of the Scientific and Technological Research Council of Turkey (TUBITAK Project Number: 113Z159) for the financial support given to the research project.
dc.identifier.doi10.1007/s11164-018-3661-0
dc.identifier.endpage1008
dc.identifier.issn0922-6168
dc.identifier.issn1568-5675
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85056462932
dc.identifier.scopusqualityQ2
dc.identifier.startpage997
dc.identifier.urihttps://doi.org/10.1007/s11164-018-3661-0
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7294
dc.identifier.volume45
dc.identifier.wosWOS:000459004900008
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorUslu, Tugce Nur
dc.institutionauthorKandemir, Hakan
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofResearch on Chemical Intermediates
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectPyrrolo carbazole
dc.subjectPhotophysical properties
dc.subjectAntioxidant activities
dc.subjectCarbazole Derivatives
dc.subjectInhibitors
dc.subjectDisease
dc.subjectAcid
dc.titleSynthesis, photophysical and antioxidant properties of pyrrolo[3,2-c]carbazole and dipyrrolo[3,2-c:2,3-g]carbazole compounds
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
7294.pdf
Boyut:
1.24 MB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Fen Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu