Supercapacitor behaviors of polyaniline/CuO, polypyrrole/CuO and PEDOT/CuO nanocomposites

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dc.authorid0000-0002-6791-7484
dc.authorid0000-0002-1806-0330
dc.authorscopusid9735216100
dc.authorscopusid56670923900
dc.authorscopusid56671315400
dc.authorscopusid56399290300
dc.authorwosidErtas, Yavuz Nuri/ABH-8904-2020
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorSerin, Mehmet Akif
dc.contributor.authorEkmen, İlker
dc.contributor.authorErtas, Yavuz N.
dc.date.accessioned2022-05-11T14:30:53Z
dc.date.available2022-05-11T14:30:53Z
dc.date.issued2015
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractPolyaniline (PANI)/copper oxide (CuO), poly(3,4-ethylenedioxythiophene) (PEDOT)/CuO and polypyrrole (PPy)/CuO have been synthesized electrochemically on glassy carbon electrode in sodium dodecyl sulfate in sulfuric acid solution as an electroactive material. To our best knowledge, the first report on comparison of supercapacitor behaviors of PANI/CuO, PEDOT/CuO and PPy/CuO nanocomposite films was studied by electrochemical impedance spectroscopy, related to the plots of Nyquist, Bode magnitude and Bode phase. The highest specific capacitance (C (sp)) was obtained as C (sp) = 286.35 F x g(-1) at the scan rate of 20 mV x s(-1) for PANI/CuO amongst the PEDOT/CuO (C (sp) = 198.89 F x g(-1) at 5 mV x s(-1)) and PPy/CuO (C (sp) = 20.78 F x g(-1) at 5 mV x s(-1)) by CV method. Long-term stability of the capacitor has also been tested by CV method, and the results indicated that, after 500 cycles, the specific capacitance of PANI/CuO nanocomposite film is 81.82 % of the initial capacitance. An equivalent circuit model of R (s)(C (dl)(R (1)(Q(R (2) W)))) has been used to fit the experimental and theoretical data.
dc.description.sponsorshipNamik Kemal University, Tekirdag, TurkeyNamik Kemal University [NKUBAP.00.10.AR.14.11]
dc.description.sponsorshipThe financial support from Namik Kemal University, Tekirdag, Turkey, project number: NKUBAP.00.10.AR.14.11 is gratefully acknowledged. Authors thank Serhat Tikiz (Afyon Kocatepe Uni., TUAM, Afyon, Turkey) for recording SEM measurements. Authors also thank Dr. Argun Gokceoren (ITU, Istanbul, Turkey) for FTIR-ATR measurements.
dc.identifier.doi10.1007/s00289-015-1422-4
dc.identifier.endpage2589
dc.identifier.issn0170-0839
dc.identifier.issn1436-2449
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-84941314614
dc.identifier.scopusqualityQ2
dc.identifier.startpage2573
dc.identifier.urihttps://doi.org/10.1007/s00289-015-1422-4
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7210
dc.identifier.volume72
dc.identifier.wosWOS:000360863400012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorSerin, Mehmet Akif
dc.institutionauthorEkmen, İlker
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofPolymer Bulletin
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectElectro-synthesis
dc.subjectPseudocapacitance
dc.subjectCuO nanoparticles
dc.subjectSupercapacitor
dc.subjectSpecific capacitance
dc.subjectConducting Polymers
dc.subjectElectrode Materials
dc.subjectOxide Film
dc.subjectImpedance
dc.subjectDevices
dc.subjectFabrication
dc.subjectStability
dc.subjectComposite
dc.titleSupercapacitor behaviors of polyaniline/CuO, polypyrrole/CuO and PEDOT/CuO nanocomposites
dc.typeArticle

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