Capacitor Applications of Nanocomposite Films for Poly(3,4-ethylenedioxythiophene-co-pyrrole)/Multi-Walled Carbon Nanotubes and Poly(3,4-ethylenedioxythiophene-co-pyrrole)/Copper Oxide

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dc.authorid0000-0002-1806-0330
dc.authorscopusid9735216100
dc.authorscopusid56671315400
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorEkmen, İlker
dc.date.accessioned2022-05-11T14:30:54Z
dc.date.available2022-05-11T14:30:54Z
dc.date.issued2016
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractPolypyrrole/multi-walled carbon nanotube, poly(3,4-ethylenedioxythiophene)/multi-walled carbon nanotube and their nanocomposites P(EDOT-co-Py)/multi-walled carbon nanotube and P(EDOT-co-Py)/copper (II) oxide, (CuO) in the initial feed ratio of [EDOT](0)/[Py](0)=1/5 were electrosynthesized on glassy carbon electrode by cyclic voltammetric method. Their characterizations were performed by cyclic voltammetric, Fourier transform infrared-attenuated total reflectance, scanning electron microscopy, energy dispersion X-ray analysis, and electrochemical impedance spectroscopy. To the best of authors' knowledge, the first report on polypyrrole/multi-walled carbon nanotube, PEDOT/multi-walled carbon nanotube, P(EDOT-co-Py)/multi-walled carbon nanotube and P(EDOT-co-Py)/CuO nanocomposite films were comparatively examined in 0.1M NaClO4/CH3CN and in 0.1M sodium dodecyl sulfate solutions. The highest specific capacitance for PEDOT/multi-walled carbon nanotube and polypyrrole/multi-walled carbon nanotube composite films were obtained as C-sp=306 mFxcm(-2) for 3% multi-walled carbon nanotube and C-sp=804 mFxcm(-2) for 1% multi-walled carbon nanotube, respectively. The highest specific capacitances were obtained as C-sp=27.40 mFxcm(-2) and C-sp=26.90 mFxcm(-2) for P(EDOT-co-Py)/multi-walled carbon nanotube includes the wt percent of 1% multi-walled carbon nanotube and P(EDOT-co-Py)/CuO includes the wt percent of 3% CuO, respectively. The C-sp of P(EDOT-co-Py)/CNT composite films were calculated as 9.43 and 11.49 mFxcm(-2) for 3 and 5% multi-walled carbon nanotube, respectively. In addition, The EIS results were simulated with the equivalent circuit model of R-s(C-dl1(R-1(QR(2))))(Cdl2R3). [GRAPHICS]
dc.description.sponsorshipNamik Kemal University, Tekirdag, TurkeyNamik Kemal University [NKUBAP.00.10.AR.14.11]
dc.description.sponsorshipThe financial support from Namik Kemal University, Tekirdag, Turkey, project number: NKUBAP.00.10.AR.14.11 is gratefully acknowledged.
dc.identifier.doi10.1080/03602559.2016.1146903
dc.identifier.endpage1502
dc.identifier.issn0360-2559
dc.identifier.issn1525-6111
dc.identifier.issue14en_US
dc.identifier.scopus2-s2.0-84986292802
dc.identifier.scopusqualityN/A
dc.identifier.startpage1489
dc.identifier.urihttps://doi.org/10.1080/03602559.2016.1146903
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7219
dc.identifier.volume55
dc.identifier.wosWOS:000382954200006
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorEkmen, İlker
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofPolymer-Plastics Technology and Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCuO
dc.subjectelectrochemistry
dc.subjectelectrochemical impedance spectroscopy
dc.subjectequivalent circuit model
dc.subjectmulti-walled carbon nanotube
dc.subjectnanocomposite
dc.subjectP(EDOT-co-Py)
dc.subjectMWCNT
dc.subjectsupercapacitor
dc.subjectConducting-Polymer
dc.subjectSupercapacitor Electrodes
dc.subjectTemplate Synthesis
dc.subjectRecent Progress
dc.subjectIonic Liquid
dc.subjectHigh-Power
dc.subjectComposites
dc.subjectPolypyrrole
dc.subjectEnergy
dc.subjectGraphene
dc.titleCapacitor Applications of Nanocomposite Films for Poly(3,4-ethylenedioxythiophene-co-pyrrole)/Multi-Walled Carbon Nanotubes and Poly(3,4-ethylenedioxythiophene-co-pyrrole)/Copper Oxide
dc.typeArticle

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