Selective oxidative deoximation with anhydrous Ce(IV) sulfate
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Dosyalar
Tarih
2015
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Anhydrous Ce(SO4)(2) in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes. (C) 2015 Elsevier Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Oxidation, Oximes, Reaction mechanism, Hammett correlation, Isonitroso hydrogen, Parent Carbonyl-Compounds, One-Pot Synthesis, Preparative Conversion, Oximes, Efficient, Regeneration, Derivatives, Nitrate
Kaynak
Tetrahedron Letters
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
56
Sayı
25
