Electrochemical Polymerization of Thiophene and Poly (3-hexyl) thiophene, Nanocomposites with TiO2, and Corrosion Protection Behaviors

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Tarih

2015

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Taylor & Francis Inc

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Thiophene, 3-hexylthiophene, and their nanocomposites with TiO2 were electropolymerized on Al1050 electrode by chronoamperometric technique. Different concentrations of thiophene and 3-hexylthiophene homopolymers and their nanocomposites with TiO2 (2% in total content) were characterized by attenuated total reflection Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersion X-ray analysis, and electrochemical impedance spectroscopy. The anticorrosion tests for homopolymers and nanocomposite films were examined on Al1050 in 3.5% NaCl solution. Poly(3-hexylthiophene)/TiO2 nanocomposite films gave the highest protection efficiency of 98% because the amount of defects was much lower than that for the poly(3-hexylthiophene), polythiophene, and polythiophene/TiO2 films.

Açıklama

Anahtar Kelimeler

Al1050, Anticorrosion, Nanocomposite, Polythiophene, Poly(3-hexylthiophene), TiO2, Conducting Polymers, Films, Polythiophene, Impedance, Surface, Steel

Kaynak

Polymer-Plastics Technology and Engineering

WoS Q Değeri

Q3

Scopus Q Değeri

N/A

Cilt

54

Sayı

17

Künye