A novel synthesis of (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole), alternating polymer formation, characterization, and capacitance measurements

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dc.authorid0000-0002-1806-0330
dc.authorid0000-0002-2819-3612
dc.authorwosidAtes, Murat/G-3798-2012
dc.authorwosiduludag, Nesimi/AAB-1353-2020
dc.contributor.authorAteş, Murat
dc.contributor.authorUludağ, Nesimi
dc.contributor.authorKarazehir, Tolga
dc.contributor.authorArican, Fatih
dc.date.accessioned2022-05-11T14:29:49Z
dc.date.available2022-05-11T14:29:49Z
dc.date.issued2013
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this work, (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole) (EDOTVBCz) comonomer was chemically synthesized and characterized by Fourier transform infrared (FTIR), proton nuclear magnetic resonance, and carbon nuclear magnetic resonance spectroscopy. EDOTVBCz was electrocoated on glassy carbon electrode (GCE) in various initial molar concentrations ([EDOTVBCz](0) = 1.0, 1.5, 2.0, and 3.0) in 0.1 M lithium perchlorate (LiClO4)/acetonitrile (CH3CN). P(EDOTVBCz)/GCE was characterized by cyclic voltammetry, FTIR reflectance-attenuated total reflection spectroscopy, scanning electron microscopy-energy dispersive X-ray analysis, atomic force microscopy, and electrochemical impedance spectroscopy (EIS). EIS was used to determine the capacitive behaviors of modified GCE via Nyquist, Bode magnitude, Bode phase, and admittance plots. The highest low-frequency capacitance value was obtained as C (LF) = similar to 2.35 mF cm(-2) for [EDOTVBCz](0) = 3.0 mM. Double-layer capacitance of the polymer/electrolyte system was calculated as C (dl) = similar to 2.78 mF cm(-2) for [EDOTVBCz](0) = 1.0 and 3.0 mM. The maximum phase angle was obtained as theta = similar to 76.7(o) for [EDOTVBCz](0) = 1.0, 1.5, 2.0, and 3.0 mM at the frequency of 20.6 Hz. AC impedance spectra of P(EDOTVBCz)/LiClO4/CH3CN was obtained by performing electrical equivalent circuit model of R(Q(R(CR))) with linear Kramers-Kronig test.
dc.description.sponsorshipScientific & Technological Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-110T791]
dc.description.sponsorshipThis work supported by The Scientific & Technological Council of Turkey (TUBITAK)-TBAG-110T791 Project.
dc.identifier.doi10.1007/s10008-013-2117-0
dc.identifier.endpage2427
dc.identifier.issn1432-8488
dc.identifier.issue9en_US
dc.identifier.startpage2417
dc.identifier.urihttps://doi.org/10.1007/s10008-013-2117-0
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7143
dc.identifier.volume17
dc.identifier.wosWOS:000323325600005
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.institutionauthorAtes, Murat
dc.institutionauthorUludağ, Nesimi
dc.institutionauthorArican, Fatih
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Solid State Electrochemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subject3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole)
dc.subjectElectrochemical impedance spectroscopy
dc.subjectSynthesis
dc.subjectEquivalent circuit model
dc.subjectDouble-layer capacitance
dc.subjectCarbon-Fiber Microelectrode
dc.subjectElectrochemical Impedance Spectroscopy
dc.subjectConjugated Polymers
dc.subjectSolar-Cells
dc.subjectPolythiophene
dc.subjectElectrode
dc.subjectElectropolymerization
dc.subjectPolyaniline
dc.subjectFilms
dc.subjectPoly(Thiophenes)
dc.titleA novel synthesis of (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9H-carbazole), alternating polymer formation, characterization, and capacitance measurements
dc.typeArticle

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