The improved diesel-like fuel from upgraded tire pyrolytic oil
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Dosyalar
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Serbian Chemical Society
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Tire pyrolytic oil (TPO) obtained from thermal pyrolysis of scrap tires is not a diesel equivalent fuel which can be used directly in vehicles due to its high density, viscosity, sulfur content, low flash point and low cetane index. It can only be used in a limited way by mixing with diesel fuel (DF) in amounts less than 30 %. In this study, the pyrolysis of scrap tires was carried out at a heating rates of 5 and 10 °C min-1 in the range of 450–600 °C, using a mixture of hierarchical zeolite (HZSM-5), mesoporous silica (MCM-41) and quicklime (CaO) as the catalyst. The obtained TPO and catalytic pyrolytic oil (CPO) were upgraded by pre-treatment, and distillation consisting of a mixture of Cu(I)-loaded mesoporous aluminosilicate (Cu(I)–MAS) and MCM-41, desulfurization and decolourization steps, respectively. To obtain diesel-like fuel, the upgraded catalytic pyrolytic oil (UCPO) and biodiesel (PBD) obtained from palm oil were blended in certain proportions. Density, viscosity, flash point and cetane index of the obtained diesel-like fuels were found within the limit values of diesel fuel. © 2022 Serbian Chemical Society. All rights reserved.
Açıklama
Anahtar Kelimeler
catalytic pyrolysis, desulfurization, mesoporous zeolite, microporous zeolite, thermal pyrolysis
Kaynak
Journal of the Serbian Chemical Society
WoS Q Değeri
Scopus Q Değeri
Q3
Cilt
87
Sayı
10
