Comparative analysis of poly(N-methylpyrrole) and its titanium dioxide nanocomposite film formations against equivalent electrical circuit model for the their corrosion-inhibition effects

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dc.authorid0000-0002-1806-0330
dc.authorid0000-0002-7528-8091
dc.authorscopusid9735216100
dc.authorscopusid56688591600
dc.authorscopusid55397552400
dc.authorwosidAtes, Murat/G-3798-2012
dc.authorwosidOzkan, Haydar/D-6009-2017
dc.authorwosidOZKAN, Haydar/U-3933-2019
dc.contributor.authorAteş, Murat
dc.contributor.authorKamer, Levent
dc.contributor.authorÖzkan, Haydar
dc.date.accessioned2022-05-11T14:30:54Z
dc.date.available2022-05-11T14:30:54Z
dc.date.issued2016
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractConducting polymers have been used for many years as coating materials against corrosion. However, the coated materials absorb water over time resulting in reduction of resistivity and anticorrosion properties. In this study, poly(N-ethylpyrrole) (P(N-MPy)) and P(N-MPy)/titanium dioxide ((TiO2) nanocomposite films were synthesized in 0.5 M oxalic acid solution on Al 1050 electrode by chronoamperometric method. The modified electrodes were characterized by scanning electron microscopy-energy dispersive X-ray analysis, Fourier transform infrared-attenuated transmission reflectance, electrochemical impedance spectroscopy (EIS), and Tafel extrapolation techniques. The corrosion tests results were obtained in 3.5% sodium chloride (NaCl) solution by Tafel plots. In addition, the equivalent electrical circuit model of P(N-MPy) and P(N-MPy)/TiO2 nanocomposite films were investigated in 3.5% NaCl solution at different time periods. The EIS study of the polymer and nanocomposite were analyzed by Matlab program and for the first time Tina, the equivalent electrical circuits program, was used.
dc.description.sponsorshipNamik Kemal University, Tekirdag, TurkeyNamik Kemal University [NKUBAP.00.10.AR.12.09]
dc.description.sponsorshipThe author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: The financial support from Namik Kemal University, Tekirdag, Turkey, project number: NKUBAP.00.10.AR.12.09, is gratefully acknowledged.
dc.identifier.doi10.1177/0954008315571682
dc.identifier.endpage84
dc.identifier.issn0954-0083
dc.identifier.issn1361-6412
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84954349775
dc.identifier.scopusqualityQ3
dc.identifier.startpage75
dc.identifier.urihttps://doi.org/10.1177/0954008315571682
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7221
dc.identifier.volume28
dc.identifier.wosWOS:000370420000008
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorKamer, Levent
dc.language.isoen
dc.publisherSage Publications Ltd
dc.relation.ispartofHigh Performance Polymers
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCorrosion
dc.subjectelectrical circuit model
dc.subjectpoly(N-methylpyrrole)
dc.subjectTiO2
dc.subjectsurface coating
dc.subjectAl 1050
dc.subjectElectrochemical Impedance Spectroscopy
dc.subjectMild-Steel
dc.subjectProtection Performance
dc.subjectPolypyrrole
dc.subjectAluminum
dc.subjectCoatings
dc.subjectComposite
dc.subjectElectropolymerization
dc.subjectPolyaniline
dc.subjectParticles
dc.titleComparative analysis of poly(N-methylpyrrole) and its titanium dioxide nanocomposite film formations against equivalent electrical circuit model for the their corrosion-inhibition effects
dc.typeArticle

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