A novel synthesis of 4-toluene 9H-carbazole-9-carbodithioate, electropolymerization and impedance study

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dc.authorid0000-0002-1806-0330
dc.authorid0000-0002-2819-3612
dc.authorscopusid9735216100
dc.authorscopusid6507868758
dc.authorscopusid54941444900
dc.authorscopusid54792801600
dc.authorwosiduludag, Nesimi/AAB-1353-2020
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorUludağ, Nesimi
dc.contributor.authorKarazehir, Tolga
dc.contributor.authorArican, Fatih
dc.date.accessioned2022-05-11T14:29:52Z
dc.date.available2022-05-11T14:29:52Z
dc.date.issued2014
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractA novel synthesis of 4-toluene 9H-carbazole-9-carbodithioate (TCzC) was chemically synthesized and characterized by Fourier Transform Infrared (FTIR), proton nuclear magnetic resonance (H-1-NMR), and carbon nuclear magnetic resonance (C-13-NMR) spectroscopies. Specific (C-sp) and double layer capacitances (C-dl) of the electro-coated poly(carbazole) and poly(TCzC) films were obtained on glassy carbon electrode (GCE) by impedimetric method with DC potential from -0.1 to + 1.0 V by increasing potential of 0.2 V. The polymers were characterized by Cyclic voltammetry (CV), Fourier transform infrared reflectance-attenuated total reflection spectroscopy (FTIR-ATR), Atomic force microscopy (AFM), and Electrochemical impedance spectroscopy (EIS). The use of additional variable (DC potential) helped to disambiguate the equivalent circuit model of R(C(R(Q(RW))))(CR). Simulation results were compared with experimental data. In this study, substituted group effects of CS2 and tosyl on carbazole polymer were investigated by EIS technique. CS2 group together with tosyl group in the structure of carbazole decreased the specific capacitance value (C-sp = 0.43 mF cm(-2)) compared to PCz (C-sp = 1.44 mF cm(-2)). Electropolymerization formation was seriously affected by substituted groups of CS2 and tosyl on conjugation system because of the electron donor and acceptor ability.
dc.description.sponsorshipScientific & Technological Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [(TUBITAK)-TBAG-110T791]
dc.description.sponsorshipThis work was supported by The Scientific & Technological Council of Turkey (TUBITAK)-TBAG-110T791 Project. Authors also thank to Yakup Bakis (Fatih University, BINATAM, Istanbul, Turkey) for recording AFM images.
dc.identifier.doi10.3144/expresspolymlett.2014.52
dc.identifier.endpage490
dc.identifier.issn1788-618X
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-84899722988
dc.identifier.scopusqualityQ2
dc.identifier.startpage480
dc.identifier.urihttps://doi.org/10.3144/expresspolymlett.2014.52
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7160
dc.identifier.volume8
dc.identifier.wosWOS:000335916200004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorUludağ, Nesimi
dc.institutionauthorKarazehir, Tolga
dc.institutionauthorArican, Fatih
dc.language.isoen
dc.publisherBudapest Univ Technol & Econ
dc.relation.ispartofExpress Polymer Letters
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectcoatings
dc.subjectfunctional polymer
dc.subjectelectrochemical impedance spectroscopy
dc.subjectelectropolymerization
dc.subjectconducting polymer
dc.subjectCarbon-Fiber Microelectrodes
dc.subjectHigh-Power Performance
dc.subjectNanostructured Polyaniline
dc.subjectComposite Electrodes
dc.subjectCyclic Voltammetry
dc.subjectSupercapacitors
dc.subjectSpectroscopy
dc.subjectPolycarbazole
dc.subjectBehavior
dc.subjectNanocomposite
dc.titleA novel synthesis of 4-toluene 9H-carbazole-9-carbodithioate, electropolymerization and impedance study
dc.typeArticle

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