Electrocoated Films of Poly(N-Methylpyrrole-co-2,2 '-Bithitiophene-co-3-(Octylthiophene)), Characterizations, and Capacitor Study

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dc.authorid0000-0002-1806-0330
dc.authorscopusid9735216100
dc.authorscopusid54792801600
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorArican, Fatih
dc.date.accessioned2022-05-11T14:30:52Z
dc.date.available2022-05-11T14:30:52Z
dc.date.issued2015
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractN-Methylpyrrole (N-MPy), 2,2 '-bithiophene (BTh), and 3-(Octylthiophene) (OTh) were electrocopolymerized in 0.2M NaClO4/CH3CN on glassy carbon electrode (GCE). The resulting terpolymers of N-MPy, BTh and OTh in different initial monomer feed ratios such as [N-MPy](0)/[BTh](0)/[OTh](0)=1/1/1 and 1/2/5 were characterized by cyclic voltammetry (CV), Fourier-transform infrared attenuated total reflectance spectroscopy (FTIR-ATR), scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), and electrochemical impedance spectroscopy (EIS). The capacitive behaviors of the modified electrodes were defined via Nyquist, Bode-magnitude, Bode-phase, and Admittance plots. The equivalent circuit model of Rs(C ( dl1 )(R ( 1 )(QR ( 2 ))))(C ( dl2 ) R ( 3 )) was performed to fit the theoretical and experimental data. The low-frequency capacitance (C-LF) were obtained from initial monomer concentrations of 50mM as C-LF=similar to 2.34x10(-4) mFcm(-2) for P(N-MPy), C-LF=5.06x10(-4) mFcm(-2) for P(BTh), C-LF=5.07 mFcm(-2) for P(OTh), and C-LF=similar to 3.78 m Fcm(-2) for terpolymer for [N-MPy](0)/[BTh](0)/[OTh](0)=1/1/1. The terpolymer may be used as energy storage devices. [GRAPHICS]
dc.description.sponsorshipResearch Foundation of Namik Kemal University (Turkey)Namik Kemal University [NKUBAP.00.10. YL.12.02]
dc.description.sponsorshipFinancial support for this work by the Research Foundation of Namik Kemal University (Turkey), project number NKUBAP.00.10. YL.12.02, is gratefully acknowledged.
dc.identifier.doi10.1080/00914037.2014.909423
dc.identifier.endpage133
dc.identifier.issn0091-4037
dc.identifier.issn1563-535X
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-84908200307
dc.identifier.scopusqualityQ2
dc.identifier.startpage125
dc.identifier.urihttps://doi.org/10.1080/00914037.2014.909423
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7199
dc.identifier.volume64
dc.identifier.wosWOS:000343605700003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorArican, Fatih
dc.language.isoen
dc.publisherTaylor & Francis As
dc.relation.ispartofInternational Journal of Polymeric Materials and Polymeric Biomaterials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectelectrochemical impedance spectroscopy
dc.subjectconducting polymers
dc.subject3-(octylthiophene)
dc.subject2,2 '-Bithitiophene
dc.subjectterpolymer
dc.subjectN-methylpyrrole
dc.subjectElectrochemical Impedance Spectroscopy
dc.subjectCarbon-Fiber Microelectrodes
dc.subjectCovalent Immobilization
dc.subjectConjugated Polymers
dc.subjectAnode Materials
dc.subjectCopolymers
dc.subjectPyrrole
dc.subjectBehavior
dc.subjectElectropolymerization
dc.subjectElectrochromism
dc.titleElectrocoated Films of Poly(N-Methylpyrrole-co-2,2 '-Bithitiophene-co-3-(Octylthiophene)), Characterizations, and Capacitor Study
dc.typeArticle

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