Synthesis of 9H-carbazole-9-carbothioic methacrylic thioanhydride, electropolymerization, characterization and supercapacitor applications

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dc.authorid0000-0002-1806-0330
dc.authorid0000-0002-2819-3612
dc.authorscopusid9735216100
dc.authorscopusid6507868758
dc.authorscopusid54792801600
dc.authorwosiduludag, Nesimi/AAB-1353-2020
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorUludağ, Nesimi
dc.contributor.authorArican, Fatih
dc.date.accessioned2022-05-11T14:29:56Z
dc.date.available2022-05-11T14:29:56Z
dc.date.issued2014
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractA novel organic molecule of 9H-carbazole-9-carbothioic methacrylic thioanhydride (CzCS(2)metac) was synthesized by incorporating CS2 and methacrylate groups into the carbazole monomer structure. CzCS(2)metac was characterized by FTIR, H-1-NMR and C-13-NMR spectroscopy. CzCS(2)metac was electropolymerized in 0.1 M tetraethylammonium tetrafluoroborate (TEABF(4))/acetonitrile (CH3CN) on glassy carbon electrode (GCE). The characterization of the electrocoated P(CzCS(2)metac)/CFME thin film was studied by various techniques, such as cyclic voltammetry, scanning electron microscopy-energy-dispersive X-ray analysis and electrochemical impedance spectroscopy. The specific capacitance (C (sp)) of P(CzCS(2)metac)/MWCNT/GCE in the scan rate of 20 mV s(-1) (C (sp) = 38.48 F g(-1) from area formula, C (sp) = 38.52 F g(-1) from charge formula) was increased similar to 15.66 and similar to 15.64 times in area and charge formulas compared to P(CzCS(2)metac)/GCE (C (sp) = 2.46 F g(-1) from area and charge formulas). The same results were also obtained from Nyquist graphs. The specific capacitance value of composite film (C (sp) = 1.09 x 10(-3) F) is similar to 15.66 times higher than the polymer film (C (sp) = 6.92 x 10(-5) F). The composite film may be used as supercapacitor electrode material in energy storage devices.
dc.description.sponsorshipScientific & Technological Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-110T791]
dc.description.sponsorshipThis work supported by The Scientific & Technological Council of Turkey (TUBITAK)-TBAG-110T791 Project.
dc.identifier.doi10.1007/s00289-014-1141-2
dc.identifier.endpage1573
dc.identifier.issn0170-0839
dc.identifier.issn1436-2449
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84901198054
dc.identifier.scopusqualityQ2
dc.identifier.startpage1557
dc.identifier.urihttps://doi.org/10.1007/s00289-014-1141-2
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7180
dc.identifier.volume71
dc.identifier.wosWOS:000335899600019
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorUludağ, Nesimi
dc.institutionauthorArıcan, Fatih
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofPolymer Bulletin
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCarbazole functionalized methacrylate
dc.subjectScanning electron microscopy
dc.subjectCapacitance
dc.subjectMulti-walled carbon nanotube
dc.subjectCarbon-Fiber Microelectrodes
dc.subjectCapacitive Behavior
dc.subjectPolymers
dc.subjectComposites
dc.subjectElectrolyte
dc.subjectNanotubes
dc.subjectFilms
dc.subjectPolymerization
dc.subjectPolycarbazole
dc.subjectFabrication
dc.titleSynthesis of 9H-carbazole-9-carbothioic methacrylic thioanhydride, electropolymerization, characterization and supercapacitor applications
dc.typeArticle

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