Monomer concentration effect on electrochemically modified carbon fiber with poly[1-(4-methoxyphenyl)-1H-pyrrole] as microcapacitor electrode
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Dosyalar
Tarih
2009
Dergi Başlığı
Dergi ISSN
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Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, films of poly[1-(4-methoxyphenyl)-1H-pyrrole] [poly(MPPy)] were electrochemically grown on carbon fiber microelectrodes (CFMEs) in 0.05 M of tetraethyl ammonium perchlorate-dichloromethane. The effect of different monomer concentrations (range = 1-10 mM) on electrochemical propert6ies of resulting polymers was characterized by cyclic voltammetry, Fourier transform infrared reflectance-attenuated total reflection spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and electrochemical impedance spectroscopy. All modified CFMEs were found to have capacitance on the basis of Nyquist, Bode-magnitude, Bode-phase, and Admittance plots. An equivalent circuit model of (R(C(R(QR)))(CR)) gave the best fit for all monomer concentrations used. Furthermore, SEM and AFM results showed that poly(MPPy) was formed as a continuous and well-adhered film onto CFME. © 2009 Wiley Periodicals, Inc.
Açıklama
Anahtar Kelimeler
Conducting polymers, Electrochemical impedance spectroscopy, Fibers, Modeling, AFM, Ammonium perchlorates, Attenuated total reflection spectroscopy, Best fit, Carbon fiber micro-electrode, Equivalent circuit model, Fourier transform infrared, Modeling, Modified carbon, Monomer concentration, Nyquist, SEM, Ammonium compounds, Atomic force microscopy, Atomic spectroscopy, Carbon fibers, Carbon films, Conducting polymers, Conductive plastics, Cyclic voltammetry, Dichloromethane, Electrochemical corrosion, Electromagnetic wave reflection, Fibers, Infrared spectroscopy, Metal analysis, Microelectrodes, Monomers, Organic conductors, Scanning electron microscopy, Electrochemical impedance spectroscopy
Kaynak
Advances in Polymer Technology
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
28
Sayı
2