Synthesis of 2-(3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9H-carbazole-9-yl)ethyl Methacrylate, Electropolymerization, Characterization and Impedimetric Study

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dc.authorid0000-0002-1806-0330
dc.authorid0000-0002-2819-3612
dc.authorscopusid9735216100
dc.authorscopusid6507868758
dc.authorscopusid54941444900
dc.authorscopusid54792801600
dc.authorwosidAtes, Murat/G-3798-2012
dc.authorwosiduludag, Nesimi/AAB-1353-2020
dc.contributor.authorAteş, Murat
dc.contributor.authorUludağ, Nesimi
dc.contributor.authorKarazehir, Tolga
dc.contributor.authorArican, Fatih
dc.date.accessioned2022-05-11T14:29:51Z
dc.date.available2022-05-11T14:29:51Z
dc.date.issued2013
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this work, 2-(3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9H-carbazole-9-yl)ethyl methacrylate (EDOTCzMetac) was chemically synthesized and characterized by FTIR, H-1-NMR, and C-13-NMR. A novel synthesized comonomer was firstly electropolymerized on glassy carbon electrode (GCE) in various initial molar concentrations [EDOTCzMetac] 0 = 1.0, 3.0, 5.0 and 10.0 mM) in 0.1 M tetraethyl ammonium tetrafluoroborate (TEABF(4))/acetonitrile (CH3CN). Poly(EDOTCzMetac)/GCE was characterized by the technique of Cyclic Voltammetry (CV), Fourier Transform Infrared Reflectance-Attenuated Total Reflection Spectroscopy (FTIR-ATR), Scanning Electron Microscopy-Energy Dispersive X-ray analysis (SEM-EDX), Atomic Force Microscope (AFM) and Electrochemical impedance spectroscopy (EIS). The capacitive behavior of modified electrode was obtained via EIS method by the help of Nyquist, Bode-magnitude, Bode-phase, and Admittance plots. The highest low frequency capacitance (C-LF) value was obtained as 4.99 mF cm(-2) for [EDOTCzMetac](0) = 10.0 mM. Therefore, the synthesized copolymer for [EDOTCzMetac](0) = 10 mM has more capacitive behavior than the initial monomer concentration for [EDOTCzMetac](0) = 1.0 mM as C-LF = 3.63 mF cm(-2), for [EDOTCzMetac](0) = 3.0 mM as C-LF = 4.10 mF cm(-2) and for [EDOTCzMetac](0) = 5.0 mM as C-LF = 4.67 mF cm(-2). To interpret the AC impedance spectra, R(C(R(Q(RW))))(CR) electrical equivalent circuit was employed with linear Kramers-Kronig test. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.011302jes] All rights reserved.
dc.description.sponsorshipScientific & Technological Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [(TUBITAK)-TBAG-110T791]
dc.description.sponsorshipThis work supported by The Scientific & Technological Council of Turkey (TUBITAK)-TBAG-110T791 Project. The authors also thank Dr. Argun Gokceoren (Istanbul Technical Uni., Istanbul, Turkey) for taking solid state conductivity measurements with Four point probe.
dc.identifier.doi10.1149/2.011302jes
dc.identifier.endpageG54
dc.identifier.issn0013-4651
dc.identifier.issn1945-7111
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84875951907
dc.identifier.scopusqualityQ1
dc.identifier.startpageG46
dc.identifier.urihttps://doi.org/10.1149/2.011302jes
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7155
dc.identifier.volume160
dc.identifier.wosWOS:000313578400061
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorUludağ, Nesimi
dc.institutionauthorKarazehir, Tolga
dc.institutionauthorArıcan, Fatih
dc.language.isoen
dc.publisherElectrochemical Soc Inc
dc.relation.ispartofJournal of the Electrochemical Society
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectElectrochemical Impedance Spectroscopy
dc.subjectCarbon-Fiber
dc.subjectSurface
dc.subjectPolyaniline
dc.subjectNanoparticles
dc.subjectMorphology
dc.subjectRedox
dc.subjectPolymerization
dc.subjectPerformance
dc.subjectThiophene
dc.titleSynthesis of 2-(3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9H-carbazole-9-yl)ethyl Methacrylate, Electropolymerization, Characterization and Impedimetric Study
dc.typeArticle

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