A Facile and Convenient Synthesis of (+/-)-Dasycarpidone
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Dosyalar
Tarih
2020
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
An efficient new pathway for (+/-)-dasycarpidone has been synthesized. The most important step in the synthesis of (+/-)-dasycarpidone is the intramolecular cyclization of the azocino[4,3-b]indole skeleton, which is constructed via tetrafluoro-1,4-benzoquinone and tetrachloro-1,4-benzoquinone and a mediated dehydrogenative cyclization of a tetrahydrocarbazole derivative possessing an amide side chain and is accomplished with high yield. The structures of all the presently synthesized compounds were confirmed using spectroscopic methods (FT-IR, H-1 NMR, C-13 NMR).
Açıklama
Anahtar Kelimeler
dasycarpidone, uleine, nordasycarpidone, azocino[4, 3-b]indole, Uleine, Route, Framework, Reduction, Alkaloids, Amines, Amides
Kaynak
Chemistry of Natural Compounds
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
56
Sayı
1
