An Improved Approach to the Synthesis of Tetracyclic 20-Deethyl-4-demethyldasycarpidone and 20-Deethyldasycarpidone

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dc.contributor.authorUludağ, Nesimi
dc.contributor.authorMutlu, H.
dc.date.accessioned2023-05-06T17:20:49Z
dc.date.available2023-05-06T17:20:49Z
dc.date.issued2022
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractAn efficient method has been reported for the synthesis of 20-deethyl-4-demethyldasycarpidone and 20-deethyldasycarpidone by tetracholoro-1,4-benzoquinone (TCB)-mediated cyclization of intermediate tetrahydrocarbazole obtained from tert-butyl [2-methyl-1-(4-methylbenzenesulfonyl)-1H-indol-3-yl]methyl carbonate. 2-[9-(4-Methylbenzenesulfonyl)-2,3,4,9-tetrahydro-1H-carbazol-2-yl]acetonitrile as the ABCD sub-struc-ture of Strychnos alkaloid family has been synthesized for the first time in a different way.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112T503]
dc.description.sponsorshipThe study was performed under financial support by the Scientific and Technological Research Council of Turkey (TUBITAK project no. 112T503).
dc.identifier.doi10.1134/S1070428022090111
dc.identifier.endpage1271
dc.identifier.issn1070-4280
dc.identifier.issn1608-3393
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-85141026665
dc.identifier.scopusqualityQ4
dc.identifier.startpage1267
dc.identifier.urihttps://doi.org/10.1134/S1070428022090111
dc.identifier.urihttps://hdl.handle.net/20.500.11776/11962
dc.identifier.volume58
dc.identifier.wosWOS:000877715800011
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorUludağ, Nesimi
dc.institutionauthorMutlu, H.
dc.language.isoen
dc.publisherMaik Nauka/Interperiodica/Springer
dc.relation.ispartofRussian Journal Of Organic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectdasycarpidone
dc.subject1
dc.subject5-methanoazocino[4
dc.subject3-b]indole
dc.subject20-deethyldasycarpidone
dc.subject20-deethyl-4-demethyldasycarpidone
dc.subjectConcise Total-Synthesis
dc.subjectEfficient Synthesis
dc.subjectUleine
dc.subjectRoute
dc.subjectAlkaloids
dc.subject2-Cyano-1,2,3,6-Tetrahydropyridines
dc.subjectAldoximes
dc.subjectFramework
dc.subjectNitriles
dc.subjectReagent
dc.titleAn Improved Approach to the Synthesis of Tetracyclic 20-Deethyl-4-demethyldasycarpidone and 20-Deethyldasycarpidone
dc.typeArticle

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