Poly(3-Octylthiophene) and Poly(3-Octylthiophene)/TiO2-Coated on Al1050: Electrosynthesis, Characterization and Its Corrosion Protection Ability in NaCl Solution

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dc.authorid0000-0002-1806-0330
dc.authorscopusid9735216100
dc.authorscopusid56418649900
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorDolapdere, Ayşegül
dc.date.accessioned2022-05-11T14:29:55Z
dc.date.available2022-05-11T14:29:55Z
dc.date.issued2014
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this study, 3-octylthiophene (3OT) and its nanocomposites with TiO2(3OT/TiO2) were electrochemically synthesized in different initial monomer concentrations (50, 75, 100, and 150mM) in 0.1M tetraethylammonium tetrafluoroborate (TEABF(4))/acetonitrile (CH3CN) on a glassy carbon electrode (GCE). The best modified electrodes, which were taken from the optimum conditions of redox behaviors, were also electropolymerized in 0.5M oxalic acid/acetonitrile (CH3CN) solution on Al1050 electrode. The modified Al1050 electrodes were characterized by optical microscope, FTIR-ATR, SEM-EDX, and EIS. The optimum conditions of the electrocoated P(3OT)/Al1050 and P(3OT)/TiO2 nanocomposites on Al1050 electrode were investigated for corrosion performances against 3.5% NaCl solution. The corrosion tests were performed by EIS and Tafel extrapolation plots together with the equivalent circuit model of R-s(Q(c)(R-c(Q(p)R(ct)))). P(3OT)/TiO2 nanocomposite films showed higher protection efficiency (PE = 89%) than P(3OT) films (PE = 81%). The P(3OT)/TiO2 nanocomposite films coated on Al1050 electrodes may be used in industrial applications of corrosion protection against salt water.
dc.description.sponsorshipNamik Kemal University, Tekirdag, TurkeyNamik Kemal University [NKUBAP.00.10. AR.12.09]
dc.description.sponsorshipThe financial support from Namik Kemal University, Tekirdag, Turkey, Project No. NKUBAP.00.10. AR.12.09 is gratefully acknowledged.
dc.identifier.doi10.1080/03602559.2014.919652
dc.identifier.endpage1777
dc.identifier.issn0360-2559
dc.identifier.issn1525-6111
dc.identifier.issue17en_US
dc.identifier.scopus2-s2.0-84910596277
dc.identifier.scopusqualityN/A
dc.identifier.startpage1768
dc.identifier.urihttps://doi.org/10.1080/03602559.2014.919652
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7175
dc.identifier.volume53
dc.identifier.wosWOS:000350410200002
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorDolapdere, Ayşegül
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofPolymer-Plastics Technology and Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCoating
dc.subjectCorrosion
dc.subjectElectropolymerization
dc.subjectNanocomposite
dc.subjectPoly(3-octylthiophene)
dc.subjectTiO2
dc.subjectElectrochemical Impedance Spectroscopy
dc.subjectThin-Films
dc.subjectMechanical-Properties
dc.subjectCarbon-Fiber
dc.subjectMild-Steel
dc.subjectTio2
dc.subjectPolyaniline
dc.subjectAluminum
dc.subjectElectrolyte
dc.subjectPerformance
dc.titlePoly(3-Octylthiophene) and Poly(3-Octylthiophene)/TiO2-Coated on Al1050: Electrosynthesis, Characterization and Its Corrosion Protection Ability in NaCl Solution
dc.typeArticle

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