Synthesis, Characterization, and Thermal Decomposition of Antimony(III) Halide Complexes of Benzaldehyde Thiosemicarbazones

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dc.contributor.authorUcar, O.
dc.contributor.authorOzturk, I. I.
dc.date.accessioned2024-10-29T17:58:46Z
dc.date.available2024-10-29T17:58:46Z
dc.date.issued2024
dc.departmentTekirdağ Namık Kemal Üniversitesi
dc.description.abstractTo investigate the coordination chemistry of the complexes formed by aromatic thiosemicarbazones with main group elements, a number of complexes of benzaldehyde-derived thiosemicarbazone ligands with antimony(III) halides were synthesized. Three new complexes were prepared by the reaction of thiosemicarbazones with antimony(III) halides in 2 : 1 molar stoichiometric ratios. The molecular structures of these complexes were revealed using spectroscopic methods. The stoichiometric ratio in the complexes was determined by the elemental analysis method. By using FT-IR, FT-Raman and 1H and 13C NMR spectroscopy methods, it was observed that thiosemicarbazones were bound in the thione form and eta 1-S coordination type and mu 2-Cl bridging bond in all complexes. Thermal stability and degradation steps due to heating were examined by thermogravimetric differential thermal analysis method (TG-DTA).
dc.description.sponsorshipTekirdag Namik Kemal University [NKUBAP.01.GA.23.452]
dc.description.sponsorshipThis work was supported by the Tekirdag Namik Kemal University (project no. NKUBAP.01.GA.23.452).
dc.identifier.doi10.1134/S107036322408019X
dc.identifier.endpage2067
dc.identifier.issn1070-3632
dc.identifier.issn1608-3350
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-85205985480
dc.identifier.scopusqualityQ4
dc.identifier.startpage2061
dc.identifier.urihttps://doi.org/10.1134/S107036322408019X
dc.identifier.urihttps://hdl.handle.net/20.500.11776/14491
dc.identifier.volume94
dc.identifier.wosWOS:001328966500012
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMaik Nauka/Interperiodica/Springer
dc.relation.ispartofRussian Journal of General Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectantimony(III) halides
dc.subjectaromatic thiosemicarbazones
dc.subjectantimony(III) complexes
dc.titleSynthesis, Characterization, and Thermal Decomposition of Antimony(III) Halide Complexes of Benzaldehyde Thiosemicarbazones
dc.typeArticle

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