Synthesis, Characterization, and Thermal Decomposition of Antimony(III) Halide Complexes of Benzaldehyde Thiosemicarbazones
Küçük Resim Yok
Tarih
2024
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Maik Nauka/Interperiodica/Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
To investigate the coordination chemistry of the complexes formed by aromatic thiosemicarbazones with main group elements, a number of complexes of benzaldehyde-derived thiosemicarbazone ligands with antimony(III) halides were synthesized. Three new complexes were prepared by the reaction of thiosemicarbazones with antimony(III) halides in 2 : 1 molar stoichiometric ratios. The molecular structures of these complexes were revealed using spectroscopic methods. The stoichiometric ratio in the complexes was determined by the elemental analysis method. By using FT-IR, FT-Raman and 1H and 13C NMR spectroscopy methods, it was observed that thiosemicarbazones were bound in the thione form and eta 1-S coordination type and mu 2-Cl bridging bond in all complexes. Thermal stability and degradation steps due to heating were examined by thermogravimetric differential thermal analysis method (TG-DTA).
Açıklama
Anahtar Kelimeler
antimony(III) halides, aromatic thiosemicarbazones, antimony(III) complexes
Kaynak
Russian Journal of General Chemistry
WoS Q Değeri
N/A
Scopus Q Değeri
Q4
Cilt
94
Sayı
8
