SYNTHESIS, CHARACTERIZATION AND HIRSHFELD SURFACE ANALYSIS OF SOME THIOSEMICARBAZONES CONTAINING A FIVE-MEMBERED RING

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dc.contributor.authorOzturk, Ibrahim I.
dc.date.accessioned2024-10-29T17:58:46Z
dc.date.available2024-10-29T17:58:46Z
dc.date.issued2023
dc.departmentTekirdağ Namık Kemal Üniversitesi
dc.description.abstractThiosemicarbazones, which are multidentate ligands, are considered as one of the most important classes of organic compounds due to their broad spectrum of pharmacological effects and their ability to coordinate easily with metal ions. Four thiosemicarbazones, furan-2-carbaldehyde-N-methyl thiosemicarbazone (Hfmtsc), thiophene-2-acetaldehyde thiosemicarbazone (Hattsc), thiophene-2-acetaldehyde-N-methyl thiosemicarbazone (Hatmtsc) and thiophene-2-acetaldehyde-N-ethyl thiosemicarbazone (Hatetsc) were successfully prepared via condensation reaction using substituted aldehyde and (un)substituted thiosemicarbazides. They were characterized by melting point, elemental analysis, molar conductivity, FTIR, UV-Vis, H-1 and C-13 NMR spectroscopic techniques. The crystal structure of them was determined by using single crystal X-ray diffraction study. Intermolecular interactions were investigated by Hirshfeld surface analysis. Molecular structure of compounds was stabilized by N-H center dot center dot center dot S, C-H center dot center dot center dot S, N-H center dot center dot center dot O and C-H center dot center dot center dot O interactions. In each compound, the molecules are connected into R-2(2)(8) dimers via pairs of N-H center dot center dot center dot S interactions.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [121Z222]; Tekirdag Namik Kemal University [NKUBAP.01.GA. 23.452]
dc.description.sponsorshipThe author is grateful to A. M. Grzeskiewicz and M. Kubicki of A. Mickiewicz University for their help in the X-ray data collection and solving the structures. This work was supported by The Scientific and Technological Research Council of Turkey (TUBITAK, Project No. 121Z222) and by the Tekirdag Namik Kemal University (Project No. NKUBAP.01.GA. 23.452).
dc.identifier.doi10.1134/S0022476623050013
dc.identifier.endpage756
dc.identifier.issn0022-4766
dc.identifier.issn1573-8779
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85160919170
dc.identifier.scopusqualityQ4
dc.identifier.startpage743
dc.identifier.urihttps://doi.org/10.1134/S0022476623050013
dc.identifier.urihttps://hdl.handle.net/20.500.11776/14488
dc.identifier.volume64
dc.identifier.wosWOS:000999902000001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPleiades Publishing Inc
dc.relation.ispartofJournal of Structural Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectthiosemicarbazones
dc.subjectspectral characterization
dc.subjectX-ray structure analysis
dc.subjectHirshfeld surface analysis
dc.titleSYNTHESIS, CHARACTERIZATION AND HIRSHFELD SURFACE ANALYSIS OF SOME THIOSEMICARBAZONES CONTAINING A FIVE-MEMBERED RING
dc.typeArticle

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