Synthesis, characterization, and biological properties of mono-, di- and poly-nuclear bismuth(III) halide complexes containing thiophene-2-carbaldehyde thiosemicarbazones

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dc.authorscopusid57890778300
dc.authorscopusid57209326301
dc.authorscopusid46860923200
dc.authorscopusid6602925165
dc.authorscopusid7005646655
dc.authorscopusid36785856200
dc.contributor.authorTürk, Kadriye
dc.contributor.authorGrzeskiewicz, Anita M.
dc.contributor.authorBanti, Christina N.
dc.contributor.authorHadjikakou, Sotiris K.
dc.contributor.authorKubicki, Maciej
dc.contributor.authorÖztürk, İbrahim İsmet
dc.date.accessioned2023-04-20T08:01:17Z
dc.date.available2023-04-20T08:01:17Z
dc.date.issued2022
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn order to investigate the coordination chemistry and pharmacological applications of bismuth compounds, a series of new bismuth(III) halide thiosemicarbazone complexes were synthesized. The reactions of thiophene-2-carbaldehyde-N-substituted thiosemicarbazones with bismuth(III) halides resulted in the formation of the {[[BiCl2(eta 1-S-Httsc)4]+.Cl-][BiCl2(mu 2-Cl)(eta 1-S-Httsc)2]2} (1), {[BiCl3(eta 1-S-Htmtsc)3].CH3OH} (2), {[BiCl3(eta 1-S-Htetsc)3].CH3OH} (3), {[BiBr2(mu 2-Br)(eta 1-S-Httsc)2]2.CH3OH} (4), {[BiBr2(mu 2-Br)(eta 1-S-Htmtsc)2]n} (5), and {[BiI2(mu 2-I)(eta 1-S-Httsc)2]2} (6) complexes (Httsc: thiophene-2-carbaldehyde thiosemicarbazone, Htmtsc: thio-phene-2-carbaldehyde-N-methyl thiosemicarbazone, Htetsc: thiophene-2-carbaldehyde-N-ethyl thio-semicarbazone). The complexes were characterized by a number of different spectroscopic techniques and the crystal structures of all bismuth(III) complexes (1-6) were determined by using single crystal X-ray diffraction study. In addition, the thermal stability of the complexes was compared using Thermogravimetric-differential thermal analysis. Crystal structures of the two free ligands, thiophene-2-carbaldehyde-N-methyl-thio-semicarbazone and thiophene-2-carbaldehyde-N-ethyl-thiosemicarbazone, were also determined by using single crystal X-ray diffraction analysis. The Hirshfeld surface of the bismuth(III) complexes and free ligands were additionally analyzed to verify the intermolecular interactions. Biological studies showed that all six bismuth(III) thiosemicarbazone complexes (1-6) exhibited biological activities against selected bacteria and the human breast adenocarcinoma (MCF-7) cell line.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK); [121Z222]
dc.description.sponsorshipAcknowledgements This research was carried out in partial fulfillment of the re-quirements for the master thesis of K.T. under the supervision of I.I.O. This work was supported by The Scientific and Technological Research Council of Turkey (TUBITAK, Project No. 121Z222) .
dc.identifier.doi10.1016/j.jinorgbio.2022.111987
dc.identifier.issn0162-0134
dc.identifier.issn1873-3344
dc.identifier.pmid36113327
dc.identifier.scopus2-s2.0-85138053468
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jinorgbio.2022.111987
dc.identifier.urihttps://hdl.handle.net/20.500.11776/10845
dc.identifier.volume237
dc.identifier.wosWOS:000862575600008
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorTürk, Kadriye
dc.institutionauthorÖztürk, İbrahim İsmet
dc.language.isoen
dc.publisherElsevier Science Inc
dc.relation.ispartofJournal of Inorganic Biochemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBismuth(Iii) Complexes
dc.subjectThiosemicarbazones
dc.subjectSynthesis
dc.subjectCharacterization
dc.subjectAntiproliferative Study
dc.subjectAntimicrobial Study
dc.subjectCrystal-Structure
dc.subjectCopper(Ii) Complexes
dc.subjectMolecular-Structures
dc.subjectAntitumor-Activity
dc.subjectMetal Derivatives
dc.subjectBonded Networks
dc.subjectIn-Vitro
dc.titleSynthesis, characterization, and biological properties of mono-, di- and poly-nuclear bismuth(III) halide complexes containing thiophene-2-carbaldehyde thiosemicarbazones
dc.typeArticle

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