Investigation of spectroscopic properties of mono and Di-styryl indole-containing BODIPYs

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dc.authorscopusid57214795961
dc.authorscopusid56531652600
dc.authorscopusid55326408200
dc.authorscopusid57201682024
dc.authorscopusid55308985300
dc.authorscopusid15135182300
dc.contributor.authorTopaloğlu Aksoy, B.
dc.contributor.authorErol, İsmail
dc.contributor.authorKandemir, Hakan
dc.contributor.authorSağlam, Mehmet F.
dc.contributor.authorŞengül, I.F.
dc.contributor.authorÇoşut, B.
dc.date.accessioned2023-04-20T08:05:59Z
dc.date.available2023-04-20T08:05:59Z
dc.date.issued2023
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn the current study, two novel mono- and distyryl BODIPYs have been successfully synthesized employing the Knoevenagel type condensation reaction between 1,3,5,7?tetramethyl BODIPY and 2,3-diphenyl-4,6-dimethoxyindole-7-carbaldehyde. This C[sbnd]C bond extension approach leads to change in hybridization of methyl carbon from sp3 to sp2 which play quite important role in the photophysical properties of BODIPYs by allowing extended conjugation. The absorption and fluorescence spectroscopy were used to determine the photophysical properties include molar extinction coefficient, fluorescence lifetime and fluorescence quantum yield. Moreover, the effect of solvent polarity on targeted BODIPY units were analysed with experimental investigations. The Density Functional Theory (DFT)-optimized structures were consisted with the experimental data obtained from the single-crystal X-ray structures. © 2022 Elsevier B.V.
dc.description.sponsorship1895206, 2094181; Gebze Teknik Üniversitesi: 2018-A105-35
dc.description.sponsorshipThis work has been supported by Research Found of the Gebze Technical University (Project Number: 2018-A105-35). The numerical calculations reported in this paper were partially performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA resources). IE acknowledges Omer Tayfuroglu and Cem Gol, for their fruitful comments/discussions on the quantum chemical calculations. The authors wish to thank Dr. A. Ingendoh and Dr. A. Koch for MALDI-TOF-MS analyses. The CCDC number 1895206 for 4 and 2094181 for 5 contain the supplementary crystallographic data (CIF) for this article. These data can be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223-336-033; e-mail: deposit@ccdc.cam. ac.uk or http://www.ccdc.cam.ac.uk).
dc.description.sponsorshipThis work has been supported by Research Found of the Gebze Technical University (Project Number: 2018-A105-35). The numerical calculations reported in this paper were partially performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA resources). IE acknowledges Omer Tayfuroglu and Cem Gol, for their fruitful comments/discussions on the quantum chemical calculations. The authors wish to thank Dr. A. Ingendoh and Dr. A. Koch for MALDI-TOF-MS analyses. The CCDC number 1895206 for 4 and 2094181 for 5 contain the supplementary crystallographic data (CIF) for this article. These data can be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223-336-033; e-mail: deposit@ccdc.cam. ac.uk or http://www.ccdc.cam.ac.uk).
dc.identifier.doi10.1016/j.ica.2022.121230
dc.identifier.issn0020-1693
dc.identifier.scopus2-s2.0-85139046974
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.ica.2022.121230
dc.identifier.urihttps://hdl.handle.net/20.500.11776/11156
dc.identifier.volume544
dc.identifier.wosWOS:000933893400003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKandemir, Hakan
dc.language.isoen
dc.publisherElsevier B.V.
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBio-supramolecular
dc.subjectBODIPY
dc.subjectDFT
dc.subjectPhotophysical
dc.subjectCondensation reactions
dc.subjectFluorescence
dc.subjectFluorescence spectroscopy
dc.subjectSingle crystals
dc.subjectSolvents
dc.subject'current
dc.subjectBio-supramolecular
dc.subjectBODIPY
dc.subjectCarbaldehydes
dc.subjectDensity-functional-theory
dc.subjectPhotophysical
dc.subjectPhotophysical properties
dc.subjectSpectroscopic property
dc.subjectSynthesised
dc.subjectTetramethyl
dc.subjectDensity functional theory
dc.titleInvestigation of spectroscopic properties of mono and Di-styryl indole-containing BODIPYs
dc.typeArticle

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