Electrochemical supercapacitors of PANI/MWCNT, PEDOT/MWCNT and P(ANI-co-EDOT)/MWCNT nanocomposites

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dc.authorid0000-0002-1806-0330
dc.authorscopusid9735216100
dc.authorscopusid56670923900
dc.authorscopusid57203991776
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorSerin, Mehmet Akif
dc.contributor.authorCalisskan, Sinan
dc.date.accessioned2022-05-11T14:31:01Z
dc.date.available2022-05-11T14:31:01Z
dc.date.issued2019
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this study, the composite formations of polyaniline (PANI)/multi-walled carbon nanotube (MWCNT), poly(3,4-ethylenedioxythiophene) (PEDOT)/MWCNT, and poly(aniline-co-3,4-ethylenedioxythiophene) (P(ANI-co-EDOT))/MWCNT were synthesized on glassy carbon electrode by cyclic voltammetry (CV) method. The composite films were characterized by CV, Fourier transform infrared-attenuated reflection spectroscopy, Raman spectroscopy, scanning electron microscopy-energy-dispersive X-ray analysis, thermogravimetric analysis-differential thermal analysis, Brunauer-Emmett-Teller surface analysis, transmission electron microscopy and electrochemical impedance spectroscopy (EIS). The modified electrodes were characterized by CV, galvanostatic charge/discharge and EIS analysis to measure the capacitance, energy and power density values. The highest specific capacitance was obtained as C-sp=590.71F/g for PANI/MWCNT at a scan rate of 50 mV/s by CV method. The PANI/MWCNT composites are promising electrode materials for high-performance electrical energy storage devices compared to PEDOT/MWCNT or P(ANI-co-EDOT)/MWCNT. The stability tests were also taken for nanocomposite films. PEDOT/MWCNT composites present excellent long cycle life with 97.44% specific capacitance retained after 500 cycles.
dc.description.sponsorshipNamik Kemal University, Tekirdag, TurkeyNamik Kemal University [NKUBAP.01.YL.15.003]
dc.description.sponsorshipThe financial support from Namik Kemal University, Tekirdag, Turkey, project number: NKUBAP.01.YL.15.003, is gratefully acknowledged.
dc.identifier.doi10.1007/s00289-018-2539-z
dc.identifier.endpage3231
dc.identifier.issn0170-0839
dc.identifier.issn1436-2449
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85053902107
dc.identifier.scopusqualityQ2
dc.identifier.startpage3207
dc.identifier.urihttps://doi.org/10.1007/s00289-018-2539-z
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7281
dc.identifier.volume76
dc.identifier.wosWOS:000464673300029
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorSerin, Mehmet Akif
dc.institutionauthorCalisskan, Sinan
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofPolymer Bulletin
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectComposites
dc.subjectNanostructures
dc.subjectEnergy storage
dc.subjectP(ANI-co-EDOT)/MWCNT
dc.subjectPANI/MWCNT
dc.subjectPEDOT/MWCNT
dc.subjectCapacitance Properties
dc.subjectConducting Polymers
dc.subjectElectrode Material
dc.subjectMesoporous Carbon
dc.subjectPolyaniline
dc.subjectComposite
dc.subjectMorphology
dc.subjectStability
dc.subjectPoly(3,4-Ethylenedioxythiophene)
dc.subjectImpedance
dc.titleElectrochemical supercapacitors of PANI/MWCNT, PEDOT/MWCNT and P(ANI-co-EDOT)/MWCNT nanocomposites
dc.typeArticle

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