Synthesis of 5-(3,6-di(thiophene-2-yl)-9H-carbazole-9-yl)pentane-1-amine and Electrochemical Impedance Spectroscopy

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dc.authorid0000-0002-1806-0330
dc.authorid0000-0002-2819-3612
dc.authorscopusid9735216100
dc.authorscopusid6507868758
dc.authorwosiduludag, Nesimi/AAB-1353-2020
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.contributor.authorUludağ, Nesimi
dc.date.accessioned2022-05-11T14:29:48Z
dc.date.available2022-05-11T14:29:48Z
dc.date.issued2012
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this article, 5-(3,6-di(thiophene-2-yl)-9H-carbazole-9-yl) pentane-1-amine, (ThCzPA) comonomer was newly synthesized and characterized by Fourier transform infrared reflectance-attenuated total reflection spectroscopy (FTIR-ATR) and H-1-NMR spectroscopy. ThCzPA was electrochemically deposited onto carbon fiber micro electrode (CFME). Poly(ThCzPA)/CFME is characterized by Cyclic voltammetry (CV) and Electrochemical impedance spectroscopy (EIS). Capacitive behaviors of modified CFMEs were defined via Nyquist, Bode-magnitude and Bode-phase plots. The equivalent circuit model of R(Q(R(QR)(Q(RW))) was used for polymer-electrolyte system. The effect of monomer concentration (0.5, 1.0 and 1.5 mM) on the formation of alternating copolymer is reported in 0.1 M sodium perchlorate (NaClO4)/acetonitrile (ACN) solution. The highest low frequency capacitance (C-LF = 5.07 mu Fcm(-2) for R(Q(R(QR)(Q(RW))) was obtained in the initial monomer concentration of 1.5 mM.
dc.description.sponsorshipThe Scientific & Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-110T516]
dc.description.sponsorshipThis work was supported by The Scientific & Technological Research Council of Turkey (TUBITAK) - TBAG-110T516 Project. The authors also thank to Prof. Dr. A. Sezai Sarac (Istanbul Technical University, Electropol. Laboratory, Istanbul, Turkey) for opportunity to use laboratory facilitates.
dc.identifier.doi10.1080/03602559.2011.651247
dc.identifier.endpage646
dc.identifier.issn0360-2559
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84860905001
dc.identifier.scopusqualityN/A
dc.identifier.startpage640
dc.identifier.urihttps://doi.org/10.1080/03602559.2011.651247
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7139
dc.identifier.volume51
dc.identifier.wosWOS:000303591800014
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorUludağ, Nesimi
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofPolymer-Plastics Technology and Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCircuit model
dc.subjectCoatings
dc.subjectElectrical properties
dc.subjectElectrochemical properties
dc.subjectThin films
dc.subjectCarbon-Fiber Microelectrodes
dc.subjectThiophene Comonomer
dc.subjectCopolymer
dc.subjectCarbazole
dc.subjectBehavior
dc.subjectPyrrole
dc.subjectStorage
dc.subjectEnergy
dc.subjectFilms
dc.subjectUnits
dc.titleSynthesis of 5-(3,6-di(thiophene-2-yl)-9H-carbazole-9-yl)pentane-1-amine and Electrochemical Impedance Spectroscopy
dc.typeArticle

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