Synthesis of 2-(9H-Carbazole-9-yl)ethyl Methacrylate: Electrochemical Impedance Spectroscopic Study of Poly(2-(9H-carbazole-9-yl)ethyl methacrylate) on Carbon Fiber

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dc.authorid0000-0002-1806-0330
dc.authorid0000-0001-7513-1740
dc.authorid0000-0002-2819-3612
dc.authorscopusid9735216100
dc.authorscopusid6507868758
dc.authorscopusid35548936600
dc.authorwosidAtes, Murat/G-3798-2012
dc.authorwosidSarac, A.Sezai/N-1628-2014
dc.authorwosiduludag, Nesimi/AAB-1353-2020
dc.contributor.authorAteş, Murat
dc.contributor.authorUludağ, Nesimi
dc.contributor.authorSaraç, A. Sezai
dc.date.accessioned2022-05-11T14:29:45Z
dc.date.available2022-05-11T14:29:45Z
dc.date.issued2011
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this contribution, 2-(9H-carbazol-9-yl)ethyl methacrylate (CzEMA) monomer was chemically synthesized. The monomer characterization was performed by FT-IR, H-1-NMR, C-13-NMR, and melting point analysis. The electropolymerization of CzEMA was studied onto carbon fiber microelectrodes (CFMEs) as an active electrode material in 0.1M sodium perchlorate (NaClO4)/acetonitrile (ACN) solution. The electropolymerization experiments were done from 1 mM to 10 mM. The detailed characterization of the resulting electrocoated Poly (CzEMA)/CFME thin films was studied by various techniques, i.e., cyclic voltammetry (CV), Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). The effects of initial monomer concentrations (1, 3, 5, and 10 mM) during the preparation of modified electrodes were examined by EIS. Capacitive behaviors of modified CFMEs were defined via Nyquist, Bode-magnitude, and Bode-phase plots. Variation of capacitance values by initial monomer concentration and specific capacitance values are presented. The highest specific capacitance value electrocoated polymer thin film by CV method in the initial monomer concentration of 5 mM with a charge of 52.74 mC was obtained about 424.1 mu F cm (2). (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 121: 3475-3482, 2011
dc.identifier.doi10.1002/app.34000
dc.identifier.endpage3482
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-79957919049
dc.identifier.scopusqualityQ2
dc.identifier.startpage3475
dc.identifier.urihttps://doi.org/10.1002/app.34000
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7123
dc.identifier.volume121
dc.identifier.wosWOS:000291613900046
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAteş, Murat
dc.institutionauthorUludağ, Nesimi
dc.language.isoen
dc.publisherWiley-Blackwell
dc.relation.ispartofJournal of Applied Polymer Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectfibers
dc.subjectcoatings
dc.subjectredox polymers
dc.subjectsynthesis
dc.subjectthin films
dc.subjectLight-Emitting-Diodes
dc.subjectDouble-Layer Capacitors
dc.subjectSurface Characterization
dc.subjectPolycarbazole
dc.subjectCarbazole
dc.subjectPolymers
dc.subjectBehavior
dc.subjectMicroelectrodes
dc.subjectDopamine
dc.subjectFilms
dc.titleSynthesis of 2-(9H-Carbazole-9-yl)ethyl Methacrylate: Electrochemical Impedance Spectroscopic Study of Poly(2-(9H-carbazole-9-yl)ethyl methacrylate) on Carbon Fiber
dc.typeArticle

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