Dual-reactive hydrogels functionalizable using Huisgen click and Schiff base reactions

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dc.contributor.authorCengiz, Nergiz
dc.date.accessioned2024-10-29T17:59:48Z
dc.date.available2024-10-29T17:59:48Z
dc.date.issued2023
dc.departmentTekirdağ Namık Kemal Üniversitesi
dc.description.abstractHydrogels incorporating different reactive groups are important platforms for the fabrication of functional materials through the conjugation of diverse molecules. In this study, a dual-reactive hydrogel system was designed utilizing aldehyde and azide groups containing methacrylate monomers. Hydrogels were obtained in the presence of a dimethacrylate crosslinker with a combination of hydrophilic PEG-based monomers via free-radical polymerization. The azide and aldehyde sites of the hydrogel network are reactive towards alkyne and amine functional groups, respectively. The advantage of the different reactivities of these functional groups was demonstrated through the attachment of two different dye molecules onto the hydrogel platform via the Huisgen click and Schiff base reactions to obtain a sensing platform for various applications, such as indicating change in pH of the environment.
dc.description.sponsorshipTekirdag~Namik Kemal University [NKUBAP.00.10.AR.15.02]
dc.description.sponsorshipThis work is supported by Tekirdag & nbsp;Namik Kemal University Research Fund (project no. NKUBAP.00.10.AR.15.02). The author also thanks Tekirdag & nbsp;Namik Kemal University Central Research Laboratory (NABILTEM) for providing help with the analysis.
dc.identifier.doi10.55730/1300-0527.3564
dc.identifier.endpage615
dc.identifier.issn1300-0527
dc.identifier.issue3en_US
dc.identifier.pmid37529222
dc.identifier.scopus2-s2.0-85164968164
dc.identifier.scopusqualityQ3
dc.identifier.startpage605
dc.identifier.trdizinid#BAŞV!
dc.identifier.urihttps://doi.org/10.55730/1300-0527.3564
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/1190395
dc.identifier.urihttps://hdl.handle.net/20.500.11776/14843
dc.identifier.volume47
dc.identifier.wosWOS:001021568600008
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakTR-Dizin
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectDual-reactive hydrogel
dc.subjectHuisgen click
dc.subjectSchiff base
dc.titleDual-reactive hydrogels functionalizable using Huisgen click and Schiff base reactions
dc.title.alternativeDual-reactive hydrogels functionalizable using “Huisgen click” and “Schiff base” reactions
dc.typeArticle

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