Supercapacitor device performances of polycarbazole/graphene and polycarbazole/nanoclay/graphene nanocomposites

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Küçük Resim

Tarih

2018

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Taylor & Francis Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In this study, graphene oxide (GO) is chemically reacted with sodium borohydride (NaBH4) to form reduced graphene oxide (rGO). rGO, polycarbazole (PCz)/rGO and PCz/nanoclay/rGO materials were obtained by chemical polymerisation method. These three materials were characterised by Fourier-transform infra-red spectroscopy-attenuated transmission reflectance, scanning electron microscopy, energy-dispersive X-ray analysis, cyclic voltammetry (CV), galvanostatic charge-discharge and electrochemical impedance spectroscopy. The PCz/nanoclay/rGO nanocomposite shows significantly improved capacitance (C-sp = 187.78 Fg(-1)) compared to that of PCz/rGO (C-sp = 74.18 Fg(-1)) and rGO (C-sp = 20.78 Fg(-1)) at the scan rate of 10 mVs(-1) by CV method. The supercapacitor device performance results show high power density (P = 1057.81 Wkg(-1)) and energy density (E = 1.7 Whkg(-1)) obtained from Ragone plot for PCz/nanoclay/rGO material. Stability tests were also examined by the CV method for 1000 cycles.

Açıklama

Anahtar Kelimeler

Reduced graphene oxide, charge/discharge, Montmorillonite nanoclay, symmetric supercapacitor, capacitance, Thin-Film, Electrochemical Properties, Electrode Materials, Energy-Storage, Graphite Oxide, Conducting Polymers, Composite Electrode, Carbon Nanotubes, Graphene Oxide, Capacitance

Kaynak

Plastics Rubber and Composites

WoS Q Değeri

Q3

Scopus Q Değeri

Q3

Cilt

47

Sayı

5

Künye