The role of operating parameters and irradiation on the electrochemical degradation of tetracycline on boron doped diamond anode in environmentally relevant matrices

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dc.authorscopusid55941188100
dc.authorscopusid7003713698
dc.contributor.authorFrontistis, Zacharias
dc.contributor.authorMeriç, Süreyya
dc.date.accessioned2022-05-11T14:17:25Z
dc.date.available2022-05-11T14:17:25Z
dc.date.issued2018
dc.departmentFakülteler, Çorlu Mühendislik Fakültesi, Çevre Mühendisliği Bölümü
dc.description.abstractBACKGROUND: Nowadays, due to the inappropriate use of antibiotics, significant quantities have been detected in environmental samples. Therefore there is a need for a technology to eliminate the accumulation of pharmaceuticals in receiving water bodies. In recent years electrochemical oxidation showed superior efficiency for the purification of water from pharmaceuticals. RESULTS: boron doped diamond (BDD) showed better efficiency than platinum electrode and stainless steel for the degradation of 500 µg L?1 tetracycline (TC) with 0.1 mol L?1·Na2SO4. The presence of 200 mg L?1 bicarbonates decreased the apparent kinetic constant from 0.328 to 0212 min?1. Instead, the addition of 200 mg L?1 NaCl increased the kinetic constant by almost four times, while the presence of 10 mg L?1 of humic acid decreased the kinetic constant by 18%. The process was favored in real environmental matrices like bottled water and wastewater in comparison with ultrapure water. The use of BDD as both anode and cathode enhanced the efficiency by almost 20%. The presence of UVA or solar radiation increased the decomposition of tetracycline by 14%. Changes in toxicity to Vibrio fisheri bacteria during treatment of TC in the secondary effluent are mainly attributed to the formation of intermediates of the water matrix itself and does not follow the TC removal. CONCLUSIONS: Electrochemical oxidation was favored for removal of TC in real water matrices due to the presence of chlorides. The use of BDD as both anode and cathode with simultaneous solar irradiation is a promising technology for water remediation from TC. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry
dc.description.sponsorshipTürkiye Bilimsel ve Teknolojik Araştirma Kurumu, TÜBITAK
dc.description.sponsorshipDr Zacharias Frontistis would like to thank the Scientific and Technological Research Council of Turkey (TUBITAK) for providing him a fellowship for conducting post-doctoral research in Namik Kemal University through the ‘2216-RESEARCH FELLOWSHIP PROGRAMME FOR INTERNATIONAL RESEARCHERS’.
dc.identifier.doi10.1002/jctb.5750
dc.identifier.endpage3655
dc.identifier.issn0268-2575
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-85051060608
dc.identifier.scopusqualityQ1
dc.identifier.startpage3648
dc.identifier.urihttps://doi.org/10.1002/jctb.5750
dc.identifier.urihttps://hdl.handle.net/20.500.11776/6353
dc.identifier.volume93
dc.indekslendigikaynakScopus
dc.institutionauthorMeriç, Süreyya
dc.language.isoen
dc.publisherJohn Wiley and Sons Ltd
dc.relation.ispartofJournal of Chemical Technology and Biotechnology
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectantibiotics
dc.subjectBDD
dc.subjectelectrochemical oxidation
dc.subjectperoxide
dc.subjecttetracycline
dc.subjectwater matrices
dc.subjectAnodes
dc.subjectAntibiotics
dc.subjectBoolean functions
dc.subjectBoron
dc.subjectCathodes
dc.subjectEfficiency
dc.subjectEffluent treatment
dc.subjectEffluents
dc.subjectElectrochemical oxidation
dc.subjectKinetics
dc.subjectPeroxides
dc.subjectSodium chloride
dc.subjectSodium sulfate
dc.subjectSolar radiation
dc.subjectBoron-doped diamond anodes
dc.subjectElectrochemical degradation
dc.subjectEnvironmental matrixes
dc.subjectOperating parameters
dc.subjectPurification of water
dc.subjectReceiving water bodies
dc.subjectTetracycline
dc.subjectWater matrices
dc.subjectIrradiation
dc.subject4,4' isopropylidenediphenol
dc.subjectbicarbonate
dc.subjectboron
dc.subjectboron doped diamond
dc.subjectcarbonic acid derivative
dc.subjectchloride
dc.subjectdeferiprone
dc.subjectdiamond
dc.subjectground water
dc.subjecthumic acid
dc.subjecthydrogen peroxide
dc.subjecthydroxyl radical
dc.subjectnatural organic matter
dc.subjectnitric acid derivative
dc.subjectorganic matter
dc.subjectplatinum
dc.subjectreactive oxygen metabolite
dc.subjectsodium chloride
dc.subjectsodium sulfate
dc.subjectstainless steel
dc.subjectsulfate
dc.subjectsurface water
dc.subjecttetracycline
dc.subjecttitanium dioxide
dc.subjectunclassified drug
dc.subjectwater
dc.subjectAliivibrio fischeri
dc.subjectArticle
dc.subjectcomparative study
dc.subjectcurrent density
dc.subjectdrug decomposition
dc.subjectecotoxicity
dc.subjecteffluent
dc.subjectelectrochemistry
dc.subjectelectrolysis
dc.subjectmineralization
dc.subjectoxidation
dc.subjectoxygen diffusion
dc.subjectoxygen evolution
dc.subjectpH
dc.subjectphotocatalysis
dc.subjectphotodegradation
dc.subjectsolar radiation
dc.subjecttotal organic carbon
dc.subjectultraviolet A radiation
dc.titleThe role of operating parameters and irradiation on the electrochemical degradation of tetracycline on boron doped diamond anode in environmentally relevant matrices
dc.typeArticle

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