Electrochemical Impedance Spectroscopic Study of Electrocoated Polythiophene and poly(2-methyl thiophene) on Carbon Fiber Microelectrode for Microcapacitor

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dc.authorid0000-0002-1806-0330
dc.authorwosidAtes, Murat/G-3798-2012
dc.contributor.authorAteş, Murat
dc.date.accessioned2022-05-11T14:29:40Z
dc.date.available2022-05-11T14:29:40Z
dc.date.issued2009
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this study, N-thiophene (T), and N-2 methylthiophene (MT) homopolymers were electrocoated on carbon fiber microelectrodes (diameter similar to 7 mu m) by cyclic voltammetry within a potential range from 0.0 to 2.0 V with well -defined parameters. All the initial monomer concentrations (from 0.1 M to 1 M) were electrodeposited in 0.1 M sodium perchlorate (NaClO4) / acetonitrile (ACN) solution and characterized by cyclic voltammetry (CV), ex-situ FTIR attenuated total reflectance spectroscopy (FTIR - ATR), and scanning electron microscopy (SEM). The electrochemical impedance spectroscopic measurements of polythiophene (PT) and poly (2-methyl thiophene) (PMT) were given comparatively. The existence of a capacitance behavior is shown by Nyquist, Bode magnitude, Bode-phase, Admittance plots relationship. The T-deposited electrode in the initial monomer concentration of 0.5 M exhibits high specific capacitance of 1.13 F g(-1), in comparison with a value of 6.35 mF g(-1) for MT modified electrode in the initial monomer concentration of 0.2 M.
dc.identifier.endpage992
dc.identifier.issn1452-3981
dc.identifier.issue7en_US
dc.identifier.startpage980
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7090
dc.identifier.volume4
dc.identifier.wosWOS:000272246000008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.institutionauthorAteş, Murat
dc.language.isoen
dc.publisherEsg
dc.relation.ispartofInternational Journal of Electrochemical Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectPolythiophene
dc.subjectmodified carbon fiber microelectrodes
dc.subjectelectrochemical impedance spectroscopy
dc.subjectPolymer-Coated Electrodes
dc.subjectFilm Electrodes
dc.subjectReactive Groups
dc.subjectConducting Polymers
dc.subjectPoly(3-Methylthiophene)
dc.subjectCopolymerization
dc.subjectComposites
dc.subjectCarbazole
dc.subjectKinetics
dc.subjectBehavior
dc.titleElectrochemical Impedance Spectroscopic Study of Electrocoated Polythiophene and poly(2-methyl thiophene) on Carbon Fiber Microelectrode for Microcapacitor
dc.typeArticle

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