Solid-to-solid polymorphic phase transitions in two isostructural Bi(III) complexes with 1-phenylethyl-N-ethylthiosemicarbazide and halogens

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dc.authoridGrzeskiewicz, Anita M./0000-0003-0377-2260
dc.contributor.authorGrzeskiewicz, Anita M.
dc.contributor.authorDutkiewicz, Grzegorz
dc.contributor.authorAygun, Ozlem
dc.contributor.authorOzturk, Ibrahim I.
dc.contributor.authorKubicki, Maciej
dc.date.accessioned2024-10-29T17:58:32Z
dc.date.available2024-10-29T17:58:32Z
dc.date.issued2023
dc.departmentTekirdağ Namık Kemal Üniversitesi
dc.description.abstractTwo isostructural (in room temperature) complexes of Bi(III) with halogens and sulfur ligands have been investigated in terms of the solid-to-solid phase transitions indicated by temperature. Both chloride and bromide (X) complexes of the general formula (& mu;(2)-X)-(BiX2L2)(2) exhibit some phase transitions between 100 and 333 K, which, apart from the numerous similarities, show significant differences, which have been noted and analyzed in detail in this paper by using different techniques, i.e., powder and single crystal diffraction or DSC. The obtained results have also been collated with those obtained for solid solutions of both complexes.
dc.identifier.doi10.1038/s41598-023-38561-4
dc.identifier.issn2045-2322
dc.identifier.issue1en_US
dc.identifier.pmid37460798
dc.identifier.scopus2-s2.0-85165198526
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1038/s41598-023-38561-4
dc.identifier.urihttps://hdl.handle.net/20.500.11776/14379
dc.identifier.volume13
dc.identifier.wosWOS:001032784200053
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherNature Portfolio
dc.relation.ispartofScientific Reports
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectProgram
dc.titleSolid-to-solid polymorphic phase transitions in two isostructural Bi(III) complexes with 1-phenylethyl-N-ethylthiosemicarbazide and halogens
dc.typeArticle

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