Selective reduction of 1,4-diarylimidazoline-3-oxides to imidazolidin-1-ols and hydroxylamine derivatives

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dc.authorscopusid35080000800
dc.authorscopusid7004177880
dc.contributor.authorAsutay, Oktay
dc.contributor.authorCoşkun, Necdet
dc.date.accessioned2022-05-11T14:47:08Z
dc.date.available2022-05-11T14:47:08Z
dc.date.issued2010
dc.departmentMeslek Yüksekokulları, Muratlı Meslek Yüksekokulu, Kimya ve Kimyasal İşleme Teknolojileri Bölümü
dc.description.abstractC-2-unsubstituted imidazoline-3-oxides were reduced with NaBH4 in THF to give the corresponding trans-3,5-diarylimidazolidin-1-ols, while under the same conditions C-2-substituted derivatives gave the corresponding ring-chain-ring tautomers. Treatment of the crude reaction mixture from the reduction of C-2-unsubstituted imidazoline-3-oxides with a MeOH-H2O mixture provided reductive C-N bond cleavage to give hydroxylamines, while under the same conditions ring-chain-ring tautomers remained unchanged.
dc.description.sponsorshipUludag UniversityUludag University [2001-2]
dc.description.sponsorshipUludag University Research Fund is gratefully acknowledged for its financial support (project no. 2001-2).
dc.identifier.doi10.1007/s00706-010-0344-y
dc.identifier.endpage905
dc.identifier.issn0026-9247
dc.identifier.issn1434-4475
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-78149414020
dc.identifier.scopusqualityQ3
dc.identifier.startpage901
dc.identifier.urihttps://doi.org/10.1007/s00706-010-0344-y
dc.identifier.urihttps://hdl.handle.net/20.500.11776/10440
dc.identifier.volume141
dc.identifier.wosWOS:000280802800011
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAsutay, Oktay
dc.language.isoen
dc.publisherSpringer Wien
dc.relation.ispartofMonatshefte Fur Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectNitrones
dc.subjectRearrangement
dc.subjectRing-chain-ring tautomers
dc.subjectSelectivity
dc.subjectHydroxylamine
dc.subjectFree-Radicals
dc.subjectNitrones
dc.subjectChemistry
dc.titleSelective reduction of 1,4-diarylimidazoline-3-oxides to imidazolidin-1-ols and hydroxylamine derivatives
dc.typeArticle

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