Establishing Composition of Solid Solution Based on Single Crystal and Powder X-ray Measurement: The Case of Halogenated Bismuth(III) Complexes with Acetophenone-4-methyl-3-thiosemicarbazone

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dc.contributor.authorGrzeskiewicz, Anita M.
dc.contributor.authorDutkiewicz, Grzegorz
dc.contributor.authorOzturk, Ibrahim I.
dc.contributor.authorKubicki, Maciej
dc.date.accessioned2024-10-29T17:59:23Z
dc.date.available2024-10-29T17:59:23Z
dc.date.issued2024
dc.departmentTekirdağ Namık Kemal Üniversitesi
dc.description.abstractNew bismuth (III) complexes with acetophenone-4-methyl-3-thiosemicarbazone (L) and halogens (Cl and Br) in both bridging and terminal positions have been synthesized and structurally characterized using single-crystal X-ray diffraction. The pure complexes (Cl or Br) were found to be highly isostructural, which motivated our attempts to create solid solutions of these complexes. A series of such compounds was prepared using various procedures and stoichiometries. A method for determining the mutual concentrations of different halogens, based on the positions of selected peaks in powder diffraction patterns, was tested and compared with other methods.
dc.identifier.doi10.3390/ijms251910814
dc.identifier.issn1661-6596
dc.identifier.issn1422-0067
dc.identifier.issue19en_US
dc.identifier.pmid39409141
dc.identifier.scopus2-s2.0-85206345156
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.3390/ijms251910814
dc.identifier.urihttps://hdl.handle.net/20.500.11776/14717
dc.identifier.volume25
dc.identifier.wosWOS:001332370700001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherMdpi
dc.relation.ispartofInternational Journal of Molecular Sciences
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectsolid solutions
dc.subjectX-ray diffraction (XRD)
dc.subjectBi complexes
dc.subjectVegard's rule
dc.titleEstablishing Composition of Solid Solution Based on Single Crystal and Powder X-ray Measurement: The Case of Halogenated Bismuth(III) Complexes with Acetophenone-4-methyl-3-thiosemicarbazone
dc.typeArticle

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