The Effect of Cr3+ Substitution on Magnetic Properties of CoFe2O4 Nanoparticles Synthesized by Microwave Combustion Route
Yükleniyor...
Dosyalar
Tarih
2016
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
CoCr (x) Fe2-x O-4 (0.0 aecurrency sign x aecurrency sign 1.0) nanoparticles were synthesized by a microwave combustion method and the effect of Cr3+ substitution on structural, morphological, and magnetic properties of CoFe2O4 was studied. The structural, morphological, and magnetic properties of the products were determined and characterized in detail by X-ray diffraction (XRD), high-resolution scanning electron microscopy (HR-SEM), energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometer (VSM). Cation distribution of calculations confirmed the B site (octahedral site) preference of substituted Cr3+ ions. X-ray analysis showed that all compositions crystallize with a cubic spinel-type structure. The lattice parameter decreased from 8.384 to 8.362 with increasing Cr content. The average crystallite size was found in the range of 30.6-45.4 nm. Magnetization measurements showed that saturation magnetization of products decreases with the increase of the Cr substitution (x).
Açıklama
Anahtar Kelimeler
CoFe2O4, Cation distribution, Magnetic properties, Cr substitution, Dielectric-Properties, Electrical-Properties, Optical-Properties, Size, Cocrxfe2-Xo4, Temperature
Kaynak
Journal of Superconductivity and Novel Magnetism
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
29
Sayı
9
