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Öğe Selective oxidative deoximation with anhydrous Ce(IV) sulfate(Pergamon-Elsevier Science Ltd, 2015) Asutay, Oktay; Hamarat, Nilufer; Uludağ, Nesimi; Coşkun, NecdetAnhydrous Ce(SO4)(2) in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes. (C) 2015 Elsevier Ltd. All rights reserved.