dc.contributor.author | Topaloğlu Aksoy, B. | |
dc.contributor.author | Erol, İsmail | |
dc.contributor.author | Kandemir, Hakan | |
dc.contributor.author | Sağlam, Mehmet F. | |
dc.contributor.author | Şengül, I.F. | |
dc.contributor.author | Çoşut, B. | |
dc.date.accessioned | 2023-04-20T08:05:59Z | |
dc.date.available | 2023-04-20T08:05:59Z | |
dc.date.issued | 2023 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | https://doi.org/10.1016/j.ica.2022.121230 | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/11156 | |
dc.description.abstract | In the current study, two novel mono- and distyryl BODIPYs have been successfully synthesized employing the Knoevenagel type condensation reaction between 1,3,5,7?tetramethyl BODIPY and 2,3-diphenyl-4,6-dimethoxyindole-7-carbaldehyde. This C[sbnd]C bond extension approach leads to change in hybridization of methyl carbon from sp3 to sp2 which play quite important role in the photophysical properties of BODIPYs by allowing extended conjugation. The absorption and fluorescence spectroscopy were used to determine the photophysical properties include molar extinction coefficient, fluorescence lifetime and fluorescence quantum yield. Moreover, the effect of solvent polarity on targeted BODIPY units were analysed with experimental investigations. The Density Functional Theory (DFT)-optimized structures were consisted with the experimental data obtained from the single-crystal X-ray structures. © 2022 Elsevier B.V. | en_US |
dc.description.sponsorship | 1895206, 2094181; Gebze Teknik Üniversitesi: 2018-A105-35 | en_US |
dc.description.sponsorship | This work has been supported by Research Found of the Gebze Technical University (Project Number: 2018-A105-35). The numerical calculations reported in this paper were partially performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA resources). IE acknowledges Omer Tayfuroglu and Cem Gol, for their fruitful comments/discussions on the quantum chemical calculations. The authors wish to thank Dr. A. Ingendoh and Dr. A. Koch for MALDI-TOF-MS analyses. The CCDC number 1895206 for 4 and 2094181 for 5 contain the supplementary crystallographic data (CIF) for this article. These data can be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223-336-033; e-mail: deposit@ccdc.cam. ac.uk or http://www.ccdc.cam.ac.uk). | en_US |
dc.description.sponsorship | This work has been supported by Research Found of the Gebze Technical University (Project Number: 2018-A105-35). The numerical calculations reported in this paper were partially performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA resources). IE acknowledges Omer Tayfuroglu and Cem Gol, for their fruitful comments/discussions on the quantum chemical calculations. The authors wish to thank Dr. A. Ingendoh and Dr. A. Koch for MALDI-TOF-MS analyses. The CCDC number 1895206 for 4 and 2094181 for 5 contain the supplementary crystallographic data (CIF) for this article. These data can be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: +44-1223-336-033; e-mail: deposit@ccdc.cam. ac.uk or http://www.ccdc.cam.ac.uk). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier B.V. | en_US |
dc.identifier.doi | 10.1016/j.ica.2022.121230 | |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Bio-supramolecular | en_US |
dc.subject | BODIPY | en_US |
dc.subject | DFT | en_US |
dc.subject | Photophysical | en_US |
dc.subject | Condensation reactions | en_US |
dc.subject | Fluorescence | en_US |
dc.subject | Fluorescence spectroscopy | en_US |
dc.subject | Single crystals | en_US |
dc.subject | Solvents | en_US |
dc.subject | 'current | en_US |
dc.subject | Bio-supramolecular | en_US |
dc.subject | BODIPY | en_US |
dc.subject | Carbaldehydes | en_US |
dc.subject | Density-functional-theory | en_US |
dc.subject | Photophysical | en_US |
dc.subject | Photophysical properties | en_US |
dc.subject | Spectroscopic property | en_US |
dc.subject | Synthesised | en_US |
dc.subject | Tetramethyl | en_US |
dc.subject | Density functional theory | en_US |
dc.title | Investigation of spectroscopic properties of mono and Di-styryl indole-containing BODIPYs | en_US |
dc.type | article | en_US |
dc.relation.ispartof | Inorganica Chimica Acta | en_US |
dc.department | Fakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.identifier.volume | 544 | en_US |
dc.institutionauthor | Kandemir, Hakan | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57214795961 | |
dc.authorscopusid | 56531652600 | |
dc.authorscopusid | 55326408200 | |
dc.authorscopusid | 57201682024 | |
dc.authorscopusid | 55308985300 | |
dc.authorscopusid | 15135182300 | |
dc.identifier.scopus | 2-s2.0-85139046974 | en_US |