dc.contributor.author | Tunçal, Tolga | |
dc.contributor.author | Çifçi, Deniz İzlen | |
dc.contributor.author | Uslu, Orhan | |
dc.date.accessioned | 2022-05-11T14:17:17Z | |
dc.date.available | 2022-05-11T14:17:17Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0926-3373 | |
dc.identifier.issn | 1873-3883 | |
dc.identifier.uri | https://doi.org/10.1016/j.apcatb.2015.05.011 | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/6295 | |
dc.description.abstract | In this study, 2,2',5,5'-tetrachlorobiphenyl removal from activated sludge matrix using thin film (TF)-based photocatalytic (PCT-TF+UVC+H2O2) and UVC+H2O2 (photolytic) treatment systems were investigated for three different initial sludge pH(i) values of 3.0 +/- 0.1; 7.3 +/- 0.1 and 10.0 +/- 0.1. A novel, visible light active Ti:Fe:Ni nano composite TF was successfully synthesized and used as catalyst. The fabricated TF was characterized by SEM, TEM, XRD, XPS and UV-vis spectroscopy methods. Experimental results indicated that while raw industrial sludge contains only 2,2',5,5''-tetrachlorobiphenyl, treated sludge samples contained more chlorinated PCB congeners in descending chlorination order from 2,2',3,3',4,4',5,5',6,6' decachlorobiphenyl to 2,3',4,4',5 pentachlorobiphenyl. Experimental results also indicated that 2,2',5,5'-tetrachlorobiphenyl was removed from the sludge matrix by only TF-based PCT that was carried out at neutral pH(i). In addition, UVC+H2O2 system caused significant PCB formation at all studied pH levels. PCB generation/degradation reactions followed pseudo-first order reaction kinetics. Obtained results also proposed that UV irradiation can induce C-Cl bond cleavage in chlorinated compounds yielding Cl-center dot radicals, responsible for further chlorination. The k(obs) value observed in 2,2',5,5'-tetrachlorobiphenyl degradation by TF-based PCT at pH(i) = 7.3 +/- 0.1 was 0.0169 +/- 10(-3) min(-1) and 1.5 times higher than at pH(i)=3.0 +/- 0.1. The observed k(obs) values in TF based PCT for PCB generation at pH(i)=3.0 +/- 0.1 and pH(i)=10.0 +/- 0.1 were 0.0037 +/- 10(-3) and 0.0015 +/- 10(-3) min(-1), respectively. (C) 2015 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [111Y209]; Cerkezkoy Organized Industrial Zone Management | en_US |
dc.description.sponsorship | This work is funded by The Scientific and Technological Research Council of Turkey TUBITAK (Project 111Y209) and Cerkezkoy Organized Industrial Zone Management. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier Science Bv | en_US |
dc.identifier.doi | 10.1016/j.apcatb.2015.05.011 | |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Tetrachlorobiphenyl | en_US |
dc.subject | Industrial sludge | en_US |
dc.subject | Thin film | en_US |
dc.subject | Photocatalytic treatment | en_US |
dc.subject | Chlorination | en_US |
dc.subject | PCBs | en_US |
dc.subject | Photocatalytic Activity | en_US |
dc.subject | Tio2 | en_US |
dc.subject | Degradation | en_US |
dc.subject | Temperature | en_US |
dc.subject | Pcbs | en_US |
dc.subject | Metal | en_US |
dc.subject | Dechlorination | en_US |
dc.subject | Deposition | en_US |
dc.subject | Oxidation | en_US |
dc.subject | Biphenyl | en_US |
dc.title | Tetrachlorobiphenyl removal from sludge matrix using mixed crystal Ti0.97Fe0.02Ni0.01O2 thin film | en_US |
dc.type | article | en_US |
dc.relation.ispartof | Applied Catalysis B-Environmental | en_US |
dc.department | Fakülteler, Çorlu Mühendislik Fakültesi, Çevre Mühendisliği Bölümü | en_US |
dc.authorid | 0000-0001-6249-5529 | |
dc.identifier.volume | 179 | en_US |
dc.identifier.startpage | 171 | en_US |
dc.identifier.endpage | 177 | en_US |
dc.institutionauthor | Tunçal, Tolga | |
dc.institutionauthor | Çifçi, Deniz İzlen | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 35176620600 | |
dc.authorscopusid | 25924855400 | |
dc.authorscopusid | 6602558250 | |
dc.authorwosid | Cifci, Deniz Izlen/AAH-3383-2020 | |
dc.authorwosid | Tolga Tunçal, Dr/AAH-2487-2019 | |
dc.identifier.wos | WOS:000359873800020 | en_US |
dc.identifier.scopus | 2-s2.0-84929464261 | en_US |