dc.contributor.author | Kandemir, Hakan | |
dc.contributor.author | Sağlam, Mehmet Turgut | |
dc.contributor.author | Şengül, İbrahim Fazıl | |
dc.date.accessioned | 2022-05-11T14:31:04Z | |
dc.date.available | 2022-05-11T14:31:04Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 1040-6638 | |
dc.identifier.issn | 1563-5333 | |
dc.identifier.uri | https://doi.org/10.1080/10406638.2018.1458739 | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/7306 | |
dc.description.abstract | The unexpected result for the formylation of N-ethylcarbazole under the Vilsmeier-Haack conditions (POCl3/DMF) led to the synthesis of novel methylene bridged bis-pyrrolo[3,2-c]carbazoles via Hemetsberger indole synthesis was reported. A plausible mechanism for the formation of unexpectedly synthesized 7,7 '-methylene bis(9-ethyl-9H-carbazole-3-carbaldehyde) 4 was postulated. The full characterization data of dicarbazolylmethane 4 and the bis-pyrrolo carbazoles 10a-b were obtained by utilizing H-1 NMR, C-13 NMR, FT-IR, mass spectrometry and single crystal X-ray diffraction techniques. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd | en_US |
dc.identifier.doi | 10.1080/10406638.2018.1458739 | |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Hemetsberger indolization | en_US |
dc.subject | methylene bridged bis-carbazole | en_US |
dc.subject | Vilsmeier-Haack formylation | en_US |
dc.subject | Carbazole Alkaloids | en_US |
dc.subject | Thermolysis | en_US |
dc.subject | Enazides | en_US |
dc.title | Synthesis of Methylene Bridged Bis-pyrrolo[3,2-c]carbazoles via an Unusual Vilsmeier-Haack Product of N-Ethylcarbazole | en_US |
dc.type | article | en_US |
dc.relation.ispartof | Polycyclic Aromatic Compounds | en_US |
dc.department | Fakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.authorid | 0000-0001-9386-4892 | |
dc.authorid | 0000-0002-7347-2223 | |
dc.identifier.volume | 40 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.startpage | 516 | en_US |
dc.identifier.endpage | 523 | en_US |
dc.institutionauthor | Kandemir, Hakan | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 55326408200 | |
dc.authorscopusid | 57201682024 | |
dc.authorscopusid | 55308985300 | |
dc.authorwosid | Sengul, Ibrahim Fazil/AAG-4368-2019 | |
dc.authorwosid | k, h/ABA-1339-2020 | |
dc.authorwosid | saglam, mehmet/Y-7456-2019 | |
dc.identifier.wos | WOS:000530941700029 | en_US |
dc.identifier.scopus | 2-s2.0-85045766095 | en_US |