dc.contributor.author | Wenholz, Daniel S. | |
dc.contributor.author | Bhadbhade, Mohan | |
dc.contributor.author | Kandemir, Hakan | |
dc.contributor.author | Ho, Junming | |
dc.contributor.author | Kumar, Naresh | |
dc.contributor.author | Black, David StC. | |
dc.date.accessioned | 2022-05-11T14:31:02Z | |
dc.date.available | 2022-05-11T14:31:02Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 1466-8033 | |
dc.identifier.uri | https://doi.org/10.1039/c8ce01757c | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/7288 | |
dc.description.abstract | Aromatic donor-acceptor stacking involving electron-rich -donors and electron-deficient -acceptors has been utilized in a broad spectrum of diverse applications to great effect. We report the discovery of unprecedented donor-acceptor stacking from a non-mixed activated benzotriazole scaffold to give cofacial -stacking in 2D sheets. We further report the effects of altering the substituents of the bicyclic aromatic system. It was found that any alteration made to the substituents disrupted the cofacial stacking, however, both aromatic donor-acceptor stacking and 2D sheet formation was observed in the solid-state assembly of the analogues. Furthermore, interactions that satisfied both electrostatic and direct-substituent -stacking models were observed. | en_US |
dc.description.sponsorship | National Health and Medical Research Council (NHMRC) AustraliaNational Health and Medical Research Council of Australia [APP1008014] | en_US |
dc.description.sponsorship | This work was supported by a Project Grant from the National Health and Medical Research Council (NHMRC) Australia to N. K. [NHMRC Grant APP1008014]. We are thankful to the Nuclear Magnetic Resonance Facility and the Bioanalytical Mass Spectrometry Facility (BMSF) in the Mark Wainwright Analytical Centre at UNSW Sydney for the opportunity of using their instruments. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Royal Soc Chemistry | en_US |
dc.identifier.doi | 10.1039/c8ce01757c | |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Donor-Acceptor Interactions | en_US |
dc.subject | Ether-Imide-Sulfones | en_US |
dc.subject | Pi-Pi Stacking | en_US |
dc.subject | Base Stacking | en_US |
dc.subject | Diimide | en_US |
dc.subject | Benzene | en_US |
dc.subject | Derivatives | en_US |
dc.subject | Packing | en_US |
dc.subject | Binding | en_US |
dc.subject | Dimer | en_US |
dc.title | Substituent effects in solid-state assembly of activated benzotriazoles | en_US |
dc.type | article | en_US |
dc.relation.ispartof | Crystengcomm | en_US |
dc.department | Fakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.authorid | 0000-0001-9381-924X | |
dc.authorid | 0000-0002-7347-2223 | |
dc.authorid | 0000-0001-9381-924X | |
dc.identifier.volume | 21 | en_US |
dc.identifier.issue | 5 | en_US |
dc.identifier.startpage | 835 | en_US |
dc.identifier.endpage | 842 | en_US |
dc.institutionauthor | Kandemir, Hakan | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57195515398 | |
dc.authorscopusid | 7003524216 | |
dc.authorscopusid | 55326408200 | |
dc.authorscopusid | 12780854300 | |
dc.authorscopusid | 16833488100 | |
dc.authorscopusid | 57217401197 | |
dc.authorwosid | Ho, Junming/A-1070-2012 | |
dc.authorwosid | k, h/ABA-1339-2020 | |
dc.authorwosid | Ho, Junming/J-9366-2019 | |
dc.identifier.wos | WOS:000458828500006 | en_US |
dc.identifier.scopus | 2-s2.0-85060804082 | en_US |