dc.contributor.author | Ateş, Murat | |
dc.contributor.author | Arican, Fatih | |
dc.date.accessioned | 2022-05-11T14:30:52Z | |
dc.date.available | 2022-05-11T14:30:52Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0091-4037 | |
dc.identifier.issn | 1563-535X | |
dc.identifier.uri | https://doi.org/10.1080/00914037.2014.909423 | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/7199 | |
dc.description.abstract | N-Methylpyrrole (N-MPy), 2,2 '-bithiophene (BTh), and 3-(Octylthiophene) (OTh) were electrocopolymerized in 0.2M NaClO4/CH3CN on glassy carbon electrode (GCE). The resulting terpolymers of N-MPy, BTh and OTh in different initial monomer feed ratios such as [N-MPy](0)/[BTh](0)/[OTh](0)=1/1/1 and 1/2/5 were characterized by cyclic voltammetry (CV), Fourier-transform infrared attenuated total reflectance spectroscopy (FTIR-ATR), scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), and electrochemical impedance spectroscopy (EIS). The capacitive behaviors of the modified electrodes were defined via Nyquist, Bode-magnitude, Bode-phase, and Admittance plots. The equivalent circuit model of Rs(C ( dl1 )(R ( 1 )(QR ( 2 ))))(C ( dl2 ) R ( 3 )) was performed to fit the theoretical and experimental data. The low-frequency capacitance (C-LF) were obtained from initial monomer concentrations of 50mM as C-LF=similar to 2.34x10(-4) mFcm(-2) for P(N-MPy), C-LF=5.06x10(-4) mFcm(-2) for P(BTh), C-LF=5.07 mFcm(-2) for P(OTh), and C-LF=similar to 3.78 m Fcm(-2) for terpolymer for [N-MPy](0)/[BTh](0)/[OTh](0)=1/1/1. The terpolymer may be used as energy storage devices. [GRAPHICS] | en_US |
dc.description.sponsorship | Research Foundation of Namik Kemal University (Turkey)Namik Kemal University [NKUBAP.00.10. YL.12.02] | en_US |
dc.description.sponsorship | Financial support for this work by the Research Foundation of Namik Kemal University (Turkey), project number NKUBAP.00.10. YL.12.02, is gratefully acknowledged. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis As | en_US |
dc.identifier.doi | 10.1080/00914037.2014.909423 | |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | electrochemical impedance spectroscopy | en_US |
dc.subject | conducting polymers | en_US |
dc.subject | 3-(octylthiophene) | en_US |
dc.subject | 2,2 '-Bithitiophene | en_US |
dc.subject | terpolymer | en_US |
dc.subject | N-methylpyrrole | en_US |
dc.subject | Electrochemical Impedance Spectroscopy | en_US |
dc.subject | Carbon-Fiber Microelectrodes | en_US |
dc.subject | Covalent Immobilization | en_US |
dc.subject | Conjugated Polymers | en_US |
dc.subject | Anode Materials | en_US |
dc.subject | Copolymers | en_US |
dc.subject | Pyrrole | en_US |
dc.subject | Behavior | en_US |
dc.subject | Electropolymerization | en_US |
dc.subject | Electrochromism | en_US |
dc.title | Electrocoated Films of Poly(N-Methylpyrrole-co-2,2 '-Bithitiophene-co-3-(Octylthiophene)), Characterizations, and Capacitor Study | en_US |
dc.type | article | en_US |
dc.relation.ispartof | International Journal of Polymeric Materials and Polymeric Biomaterials | en_US |
dc.department | Fakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.authorid | 0000-0002-1806-0330 | |
dc.identifier.volume | 64 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.startpage | 125 | en_US |
dc.identifier.endpage | 133 | en_US |
dc.institutionauthor | Ateş, Murat | |
dc.institutionauthor | Arican, Fatih | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 9735216100 | |
dc.authorscopusid | 54792801600 | |
dc.authorwosid | Ates, Murat/G-3798-2012 | |
dc.identifier.wos | WOS:000343605700003 | en_US |
dc.identifier.scopus | 2-s2.0-84908200307 | en_US |