dc.contributor.author | Ateş, Murat | |
dc.contributor.author | Uludağ, Nesimi | |
dc.date.accessioned | 2022-05-11T14:29:51Z | |
dc.date.available | 2022-05-11T14:29:51Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1385-772X | |
dc.identifier.issn | 1568-5551 | |
dc.identifier.uri | https://doi.org/10.1080/15685551.2012.747157 | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/7156 | |
dc.description.abstract | In this paper, 6-(3,6-di(thiophene-2-yl)-9H-carbazole-9-yl)-hexanoic acid (ThCzHa) comonomer was newly synthesized and characterized with Fourier transform infrared spectroscopy (FTIR) and H-1-NMR. The synthesized comonomer was electrochemically deposited onto carbon fiber microelectrode (CFME). An electrochemical impedance study on the prepared electrodes is reported. Poly(ThCzHa)/CFME is characterized by cyclic voltammetry (CV), Fourier transform infrared reflectance-attenuated total reflection spectroscopy (FTIR-ATR), scanning electron microscopyenergy dispersive X-ray analysis (SEMEDX), and electrochemical impedance spectroscopy. Capacitive behaviors of modified CFMEs were defined via Nyquist, Bode-magnitude, Bode-phase, and Admittance plots. The equivalent circuit model of R(Q(R(C(R(C(RW))))))(CR) was examined for polymer/electrolyte system. The effect of initial monomer concentration (0.5, 1.0 and 1.5mM) on the formation of alternating copolymer is reported in 0.1M sodium perchlorate/acetonitrile solution. The copolymer structure was also characterized by FTIR-ATR, SEMEDX, and CV measurements. The highest low frequency capacitance (C-LF=5.2mFcm(2)), double layer capacitance (C-dl=100Fcm(2)) and maximum phase angle approximate to 82(o) at the frequency of 0.1Hz were obtained for [ThCzHa](0)=0.5mM. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-110T516] | en_US |
dc.description.sponsorship | This work was supported by the Scientific and Technological Research Council of Turkey (TUBITAK)-TBAG-110T516 Project. The authors thank Prof. Dr A.S. Sarac (ITU, Electropol Lab, Istanbul, Turkey), O. Oskan (Afyon Kocatepe Uni, TUAM, Afyon, Turkey), and Dr A. Gokceoren for the opportunity to use lab facilities, SEM-EDX analysis, and conductivity measurements, respectively. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd | en_US |
dc.identifier.doi | 10.1080/15685551.2012.747157 | |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | polymers | en_US |
dc.subject | thin films | en_US |
dc.subject | electrical properties | en_US |
dc.subject | electrochemical properties | en_US |
dc.subject | synthesis | en_US |
dc.subject | Carbon-Fiber Microelectrodes | en_US |
dc.subject | Electrochemical-Behavior | en_US |
dc.subject | Conjugated Polymers | en_US |
dc.subject | Conducting Polymers | en_US |
dc.subject | N-Methylpyrrole | en_US |
dc.subject | Thin-Films | en_US |
dc.subject | Electrode | en_US |
dc.subject | Electropolymerization | en_US |
dc.subject | Polypyrrole | en_US |
dc.subject | Polyaniline | en_US |
dc.title | Synthesis of 6-(3,6-di(thiophene-2-yl)-9H-carbazole-9-yl)-hexanoic acid, alternating copolymer formation, characterization and impedance evaluations | en_US |
dc.type | article | en_US |
dc.relation.ispartof | Designed Monomers and Polymers | en_US |
dc.department | Fakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.authorid | 0000-0002-1806-0330 | |
dc.authorid | 0000-0002-2819-3612 | |
dc.identifier.volume | 16 | en_US |
dc.identifier.issue | 4 | en_US |
dc.identifier.startpage | 398 | en_US |
dc.identifier.endpage | 406 | en_US |
dc.institutionauthor | Ateş, Murat | |
dc.institutionauthor | Uludağ, Nesimi | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 9735216100 | |
dc.authorscopusid | 6507868758 | |
dc.authorwosid | Ates, Murat/G-3798-2012 | |
dc.authorwosid | uludag, Nesimi/AAB-1353-2020 | |
dc.identifier.wos | WOS:000317841500011 | en_US |
dc.identifier.scopus | 2-s2.0-84878028371 | en_US |