dc.contributor.author | Gürkan, Yelda Yalçın | |
dc.contributor.author | Türkten, Nazlı | |
dc.contributor.author | Hatipoğlu, A. | |
dc.contributor.author | Çınar, Zekiye | |
dc.date.accessioned | 2022-05-11T14:29:47Z | |
dc.date.available | 2022-05-11T14:29:47Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1385-8947 | |
dc.identifier.uri | https://doi.org/10.1016/j.cej.2012.01.011 | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/7134 | |
dc.description.abstract | Cefazolin is a semi-synthetic antibiotic found in aqueous environments as a pollutant due to its widespread use. The photocatalytic degradation of cefazolin was investigated in aqueous N-doped and undoped-TiO 2 suspensions under both UV and sunlight irradiation. N-doped TiO 2 photocatalysts with different nitrogen contents were prepared by an incipient wet impregnation method. Characterization of the N-doped samples was performed by SEM-EDX, XRD, UV-DRS, XPS, Raman spectroscopy and surface area (BET) measurements. Degradation of cefazolin was achieved with the use of UV/TiO 2. 53% degradation was obtained in 60min. A higher photocatalytic activity for the degradation of cefazolin was obtained for the N-doped TiO 2 compared to Degussa P25. 76% of cefazolin was degraded in 50min. The N-doped TiO 2 also exhibited substantial photocatalytic activity under direct sunlight irradiation, with 80% of cefazolin removed in 30min. The photocatalytic degradation reaction of cefazolin was monitored by HPLC and FT-IR analyses. The photocatalytic degradation mechanism of cefazolin was determined by the application of the conceptual DFT. The DFT descriptors combined with the experimental results indicate that degradation of cefazolin occurs through intramolecular ?-lactam, thiadiazole, tetrazole and dihydrothiazine ring cleavages followed by subsequent reactions with OH radicals transforming the fragments into smaller species such as SO 4 2-, NO 3 - and NH 4 +. The predicted mechanism was confirmed by comparison with the experimental results on simple structures reported in the literature. © 2012 Elsevier B.V. | en_US |
dc.description.sponsorship | 29-01-02-KAP01 | en_US |
dc.description.sponsorship | The authors express their thanks to Yıldız Technical University Research Foundation for financial support (Project no: 29-01-02-KAP01), to Degussa Limited Company in Turkey for the generous gift of TiO 2 and to PharmaVision Pharmaceutical Company for providing cefazolin Na. Special thanks are due to Korhan BAHAR (M.Sc. in Chem.) for HPLC analyses. | en_US |
dc.language.iso | eng | en_US |
dc.identifier.doi | 10.1016/j.cej.2012.01.011 | |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Cefazolin | en_US |
dc.subject | Heterogeneous photocatalysis | en_US |
dc.subject | Nitrogen doping | en_US |
dc.subject | Sunlight | en_US |
dc.subject | TiO 2 | en_US |
dc.subject | UV-light | en_US |
dc.subject | Cefazolin | en_US |
dc.subject | Heterogeneous photocatalysis | en_US |
dc.subject | Nitrogen doping | en_US |
dc.subject | Sunlight | en_US |
dc.subject | TiO | en_US |
dc.subject | UV-light | en_US |
dc.subject | Degradation | en_US |
dc.subject | Free radicals | en_US |
dc.subject | Irradiation | en_US |
dc.subject | Photocatalysis | en_US |
dc.subject | Photocatalysts | en_US |
dc.subject | Photodegradation | en_US |
dc.subject | Raman spectroscopy | en_US |
dc.subject | Suspensions (fluids) | en_US |
dc.subject | Titanium dioxide | en_US |
dc.title | Photocatalytic degradation of cefazolin over N-doped TiO 2 under UV and sunlight irradiation: Prediction of the reaction paths via conceptual DFT | en_US |
dc.type | article | en_US |
dc.relation.ispartof | Chemical Engineering Journal | en_US |
dc.department | Fakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.identifier.volume | 184 | en_US |
dc.identifier.startpage | 113 | en_US |
dc.identifier.endpage | 124 | en_US |
dc.institutionauthor | Gürkan, Yelda Yalçın | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 54911752000 | |
dc.authorscopusid | 54911900700 | |
dc.authorscopusid | 6701388208 | |
dc.authorscopusid | 6603153611 | |
dc.identifier.scopus | 2-s2.0-84857031311 | en_US |