dc.contributor.author | Ateş, Murat | |
dc.date.accessioned | 2022-05-11T14:29:40Z | |
dc.date.available | 2022-05-11T14:29:40Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 1452-3981 | |
dc.identifier.uri | https://hdl.handle.net/20.500.11776/7090 | |
dc.description.abstract | In this study, N-thiophene (T), and N-2 methylthiophene (MT) homopolymers were electrocoated on carbon fiber microelectrodes (diameter similar to 7 mu m) by cyclic voltammetry within a potential range from 0.0 to 2.0 V with well -defined parameters. All the initial monomer concentrations (from 0.1 M to 1 M) were electrodeposited in 0.1 M sodium perchlorate (NaClO4) / acetonitrile (ACN) solution and characterized by cyclic voltammetry (CV), ex-situ FTIR attenuated total reflectance spectroscopy (FTIR - ATR), and scanning electron microscopy (SEM). The electrochemical impedance spectroscopic measurements of polythiophene (PT) and poly (2-methyl thiophene) (PMT) were given comparatively. The existence of a capacitance behavior is shown by Nyquist, Bode magnitude, Bode-phase, Admittance plots relationship. The T-deposited electrode in the initial monomer concentration of 0.5 M exhibits high specific capacitance of 1.13 F g(-1), in comparison with a value of 6.35 mF g(-1) for MT modified electrode in the initial monomer concentration of 0.2 M. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Esg | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Polythiophene | en_US |
dc.subject | modified carbon fiber microelectrodes | en_US |
dc.subject | electrochemical impedance spectroscopy | en_US |
dc.subject | Polymer-Coated Electrodes | en_US |
dc.subject | Film Electrodes | en_US |
dc.subject | Reactive Groups | en_US |
dc.subject | Conducting Polymers | en_US |
dc.subject | Poly(3-Methylthiophene) | en_US |
dc.subject | Copolymerization | en_US |
dc.subject | Composites | en_US |
dc.subject | Carbazole | en_US |
dc.subject | Kinetics | en_US |
dc.subject | Behavior | en_US |
dc.title | Electrochemical Impedance Spectroscopic Study of Electrocoated Polythiophene and poly(2-methyl thiophene) on Carbon Fiber Microelectrode for Microcapacitor | en_US |
dc.type | article | en_US |
dc.relation.ispartof | International Journal of Electrochemical Science | en_US |
dc.department | Fakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.authorid | 0000-0002-1806-0330 | |
dc.identifier.volume | 4 | en_US |
dc.identifier.issue | 7 | en_US |
dc.identifier.startpage | 980 | en_US |
dc.identifier.endpage | 992 | en_US |
dc.institutionauthor | Ateş, Murat | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorwosid | Ates, Murat/G-3798-2012 | |
dc.identifier.wos | WOS:000272246000008 | en_US |