Ucar, O.Ozturk, I. I.2024-10-292024-10-2920241070-36321608-3350https://doi.org/10.1134/S107036322408019Xhttps://hdl.handle.net/20.500.11776/14491To investigate the coordination chemistry of the complexes formed by aromatic thiosemicarbazones with main group elements, a number of complexes of benzaldehyde-derived thiosemicarbazone ligands with antimony(III) halides were synthesized. Three new complexes were prepared by the reaction of thiosemicarbazones with antimony(III) halides in 2 : 1 molar stoichiometric ratios. The molecular structures of these complexes were revealed using spectroscopic methods. The stoichiometric ratio in the complexes was determined by the elemental analysis method. By using FT-IR, FT-Raman and 1H and 13C NMR spectroscopy methods, it was observed that thiosemicarbazones were bound in the thione form and eta 1-S coordination type and mu 2-Cl bridging bond in all complexes. Thermal stability and degradation steps due to heating were examined by thermogravimetric differential thermal analysis method (TG-DTA).en10.1134/S107036322408019Xinfo:eu-repo/semantics/closedAccessantimony(III) halidesaromatic thiosemicarbazonesantimony(III) complexesArticle94820612067N/AWOS:0013289665000122-s2.0-85205985480Q4