Grzeskiewicz, Anita M.Dutkiewicz, GrzegorzOzturk, Ibrahim I.Kubicki, Maciej2024-10-292024-10-2920241661-65961422-0067https://doi.org/10.3390/ijms251910814https://hdl.handle.net/20.500.11776/14717New bismuth (III) complexes with acetophenone-4-methyl-3-thiosemicarbazone (L) and halogens (Cl and Br) in both bridging and terminal positions have been synthesized and structurally characterized using single-crystal X-ray diffraction. The pure complexes (Cl or Br) were found to be highly isostructural, which motivated our attempts to create solid solutions of these complexes. A series of such compounds was prepared using various procedures and stoichiometries. A method for determining the mutual concentrations of different halogens, based on the positions of selected peaks in powder diffraction patterns, was tested and compared with other methods.en10.3390/ijms251910814info:eu-repo/semantics/openAccesssolid solutionsX-ray diffraction (XRD)Bi complexesVegard's ruleArticle2519N/AWOS:0013323707000012-s2.0-8520634515639409141Q1