Azaindole-BODIPYs: Synthesis, fluorescent recognition of hydrogen sulfate anion and biological evaluation

dc.authorid0000-0001-6325-5674
dc.authorid0000-0002-7812-6872
dc.authorid0000-0002-3579-8062
dc.authorid0000-0001-9386-4892
dc.authorid0000-0002-7347-2223
dc.authorid0000-0001-6530-0205
dc.authorscopusid54880561700
dc.authorscopusid57201377761
dc.authorscopusid55874720500
dc.authorscopusid56884511100
dc.authorscopusid35487408100
dc.authorscopusid34168278000
dc.authorscopusid55308985300
dc.authorwosidÖzcan, Emrah/AAL-1301-2020
dc.authorwosidKESAN, Gurkan/F-3306-2017
dc.authorwosidSengul, Ibrahim Fazil/AAG-4368-2019
dc.authorwosidŞenkuytu, Elif/ABI-5315-2020
dc.authorwosidk, h/ABA-1339-2020
dc.authorwosidÇOŞUT, Bünyemin/X-7554-2019
dc.contributor.authorKesan, Gurkan
dc.contributor.authorTopaloglu, Burcu
dc.contributor.authorÖzcan, Emrah
dc.contributor.authorKazan, Hasan Huseyin
dc.contributor.authorEcik, Esra Tanriverdi
dc.contributor.authorŞenkuytu, Elif
dc.contributor.authorCosut, Bunyemin
dc.contributor.authorKandemir, Hakan
dc.date.accessioned2022-05-11T14:31:01Z
dc.date.available2022-05-11T14:31:01Z
dc.date.issued2019
dc.departmentFakülteler, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractThe synthesized and sensing capability of two novel azaindole substituted mono and distyryl BODIPY dyes against bisulfate anion were reported. Structural characterizations of the targeted compounds were conducted by using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, H-1 and C-13 NMRspectroscopies. Photophysical properties of the azaindole substituted BODIPY compounds were investigated employing absorption and fluorescence spectroscopies in acetonitrile solution. It was found that the final compounds 3 and 4 exhibited exclusively selective and sensitive turn-off sensor behavior on HSO4- anion. Additionally, the stoichiometry ratio of the targeted compounds to bisulfate anion was measured 0.5 by Job's method. Also, density function theory was performed to the optical response of the sensor for targeted compounds. Furthermore, the cytotoxicity of Azaindole-BODIPYs was examined against living human leukemia K562 cell lines. (C) 2019 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.saa.2019.01.047
dc.identifier.endpage82
dc.identifier.issn1386-1425
dc.identifier.issn1873-3557
dc.identifier.pmid30684882
dc.identifier.scopus2-s2.0-85060282987
dc.identifier.scopusqualityQ2
dc.identifier.startpage73
dc.identifier.urihttps://doi.org/10.1016/j.saa.2019.01.047
dc.identifier.urihttps://hdl.handle.net/20.500.11776/7278
dc.identifier.volume213
dc.identifier.wosWOS:000471314400011
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorKandemir, Hakan
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofSpectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBorondipyrromethenes
dc.subjectAzaindole
dc.subjectHydrogen sulfate
dc.subjectAnionsensor
dc.subjectFluorescence
dc.subjectChemosensor
dc.subjectK562 cell lines
dc.subjectDFT
dc.subjectEfficient Energy-Transfer
dc.subjectPhotophysical Properties
dc.subjectAqueous-Solution
dc.subjectDyes Synthesis
dc.subjectSensor
dc.subjectDesign
dc.subjectChemosensor
dc.titleAzaindole-BODIPYs: Synthesis, fluorescent recognition of hydrogen sulfate anion and biological evaluation
dc.typeArticle

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