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    Evolving a Methodology for Assessing Pesticide Pressure on Water Bodies under Data Scarce Conditions: A Case Study on the Marmara Basin in Türkiye
    (Mdpi, 2024) Hanedar, Asude; Girgin, Emine; Karaaslan, Yakup; Tanik, Aysegul
    In this study, current pesticide use was determined on the basis of active substances (ASs) in each water body in the Marmara Basin, which is the most crowded region of Turkiye and where agriculture is intensive. The risks of detected pesticide ASs were then categorized in terms of usage amount, water body monitoring results, and hazardous characteristics. At the same time, a system was proposed for determining pesticide use on an AS basis, based on the product planted in districts that do not have detailed information on AS use. Finally, a methodology for assessing pesticide pressure on water bodies was developed by utilizing pesticide risk based on the determined AS types under data scarcity conditions. The topic undertaken is current and extremely important in the era of food safety, and is related to growing pressure on water, on one hand, and human health and quality of food products, on the other. Data based on ASs are hard to record and store, particularly in developing countries; therefore, a data inventory was initially realized in the study as an essential step towards an assessment procedure. The easy-to-use pesticide pressure determination methodology was developed and applied to the Marmara Basin of Turkiye, ensuring compliance with the Water framework Directive (WFD) and EU Green Deal. Constraints experienced during the application of the developed methodology are put forth with the intention of providing utilizable information to those international scientists who will be interested in practicing it in the future. Therefore, transposition of the methodology to other basins in different countries will be possible. According to 2021 data, 0.04-8.83 kg/ha pesticide and 173 pesticide active substances were used in the basin. ASs were prioritized over four criteria based on the amount of use, hazardous properties, and monitoring results. Consequently, 52 active substances were determined and included in the risk group. Taking these criteria into consideration, all the 276 agricultural water bodies in the basin were revealed to be under pesticide pressure.
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    Prioritization methodology of dangerous substances for water quality monitoring with scarce data
    (Springer, 2017) Karahan Özgün, Özlem; Başak, Bertan; Eropak, Ceren; Abat, Seda; Kırım, Gamze; Girgin, Emine; Koç Orhon, Aybala; Hanedar, Asude; Güneş, Elçin
    Monitoring and control of dangerous substances discharged into receiving waters have attracted more attention lately. Since it is not possible to analyze every single substance, a prioritization methodology is needed for the selection of those to be monitored. Existing well-developed models require significant amount of data for reliable outcomes. This paper presents a methodology to prioritize the dangerous substances having adverse effects on freshwaters in Turkey, where data are scarce. Such a methodology will also serve as a solid model for other countries with limited background data. The adopted methodology enabled the elimination of chemicals to generate a candidate list composed of 608 substances among more than 5000 substances. Further screening and prioritization were conducted using different assessment methods (i.e., Total Hazard Value, Total Impact Value, Combined Monitoring-based, and Modelling-based Priority Setting) to obtain a proposed Final Candidate Specific Pollutants List of 150 dangerous substances. The proposed Candidate National Pollutant List of Turkey was established by combining 45 priority pollutants of the European Union with a list of candidate specific pollutants. According to the outcomes of this study, monitoring and controlling of 195 dangerous substances in freshwaters are recommended. Further detailed studies should be conducted in order to observe the actual levels of these dangerous substances in freshwaters followed by a review of the monitoring list accordingly. Moreover, further revisions might be required in the proposed list due to some possible versatile conditions in terms of sampling points (i.e., change in the location of industries).
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    Utility of a source-related matrix in basin management studies: a practice on a sub-Basin in Turkey
    (Springer Heidelberg, 2021) Hanedar, Asude; Tanik, Ayşegül; Girgin, Emine; Güneş, Elçin; Karakaya, Nusret; Gorgun, Erdem; Dikmen, Bilal
    According to the water framework directive (WFD), the chemical status should be determined for each water body in a basin through monitoring and evaluation studies, and the gap between the status of water bodies and good water status should be revealed in river basin management plans. In this context, the methodology starting with the evaluation of the monitoring results of the priority substances (PSs) until the end of determining the measures to achieve good condition in surface waters was given in this study. The key aim was to provide a useful methodology defined as a matrix for determining the sources of pollutants that caused this gap. This matrix was applied to the most polluted sub-basin of Kucuk Menderes Basin located on the western part of the Turkey. Monitoring studies were carried out in 21 water bodies for a 1-year period for 45 PSs and monitoring results were compared with environmental quality standards (EQS). It was determined that 13 of 45 PSs in 15 water bodies exceeded the EQS. The common PSs in the basin were lead, nickel, fluoranthene, benzo(a)pyrene, C10-13 chloroalkanes, and 4-nonylphenols and average rates of exceeding the EQS were 58.3%, 36.4%, 91.5%, 99.9%, 74.8%, and 49.4%, respectively. The detailed emission inventory of each water body in the basin has been made. Potential sources of PSs were searched via the matrix formed and a total number of 420 basic and supplementary measures were proposed to improve the water quality of the sub-basin.